Abstract
The new complexes [M(CO)5-DABRd] [M=Cr; 1, Mo; 2, W; 3], [cis-Re(CO)4Br-DABRd] (4), [M(CO)5-BRd] [M=Cr; 5, Mo; 6, W; 7] and [Mo(CO)5-L] [L=Rd, 8; 2CBRd, 9; 2HNARd, 10; IBRd, 11] have been synthesized by the photochemical reactions of VIB and VIIB group metal carbonyls [M(CO)6] [M=Cr, Mo, W] and [Re(CO)5Br] with 5-(4-dimethylaminobenzylidene)rhodanine (DABRd), 5-benzylidenerhodanine (BRd), rhodanine (Rd), 5-(2-chlorobenzylidene)rhodanine (2CBRd), 5-(2- hydroxynaphtylidene)rhodanine (2HNARd), 5-(4-isopropylbenzylidene)rhodanine (IBRd) and characterized by elemental analysis, FT-IR, 1H and 13C-{1H}-NMR spectroscopy and by Mass spectrometry. The spectroscopic studies show that all rhodanine ligands act as monodentate ligands coordinating via the sulfur (CS) donor atom in (1-11).
Original language | English |
---|---|
Pages (from-to) | 705-711 |
Number of pages | 7 |
Journal | Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry |
Volume | 36 |
Issue number | 10 |
DOIs | |
Publication status | Published - 1 Dec 2006 |
Funding
We thank BP (Turkey) for the provision of photochemical apparatus and Research Foundation of Ege and Dokuz Eylul University for funds. We thank TUBITAK for allocation of time at the Mass Spectra and Elemental Analyses. We thank Dr. Yurdanur Yayla for obtaining 1Hand 13C-f1Hg-NMR. spectra at Ege University. This work also supported by Research Fund of Istanbul University, Project Number: 818/190496, and Dokuz Eylul University, Project Number: 04.KB.FEN.106.
Funders | Funder number |
---|---|
Research Foundation of Ege and Dokuz Eylul University | |
BP | |
Istanbul Üniversitesi | 818/190496 |
Dokuz Eylül Üniversitesi | KB.FEN.106 |
Keywords
- 5-benzylidenerhodanines
- Metal carbonyl complexes
- Organometallic compounds
- Rhodanine (4-thiazolidinone-2-thioxo)