Photo-initiated cationic polymerization of cyclohexene oxide using photosensitive polymers having benzoin side-groups in the presence of pyridinium salt

Aysen Onen; Yusuf Yagci

doi:10.1016/0014-3057(92)90074-C

Photo-initiated cationic polymerization of cyclohexene oxide using photosensitive polymers having benzoin side-groups in the presence of pyridinium salt

Aysen Onen, Yusuf Yagci^*

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

The photolysis of poly(benzoin acrylate) at γ > 350 nm leads to polymer-bound free radicals which can be oxidized by pyridinium ions. The resulting ionic species are capable of readily initiating the cationic polymerization of cyclohexene oxide (CHO). Photografting of copolymers containing styrene and benzoin acrylate with CHO gave a crosslinked product.

Original language	English
Pages (from-to)	721-723
Number of pages	3
Journal	European Polymer Journal
Volume	28
Issue number	7
DOIs	https://doi.org/10.1016/0014-3057(92)90074-C
Publication status	Published - Jul 1992

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10.1016/0014-3057(92)90074-C

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title = "Photo-initiated cationic polymerization of cyclohexene oxide using photosensitive polymers having benzoin side-groups in the presence of pyridinium salt",

abstract = "The photolysis of poly(benzoin acrylate) at γ > 350 nm leads to polymer-bound free radicals which can be oxidized by pyridinium ions. The resulting ionic species are capable of readily initiating the cationic polymerization of cyclohexene oxide (CHO). Photografting of copolymers containing styrene and benzoin acrylate with CHO gave a crosslinked product.",

author = "Aysen Onen and Yusuf Yagci",

year = "1992",

month = jul,

doi = "10.1016/0014-3057(92)90074-C",

language = "English",

volume = "28",

pages = "721--723",

journal = "European Polymer Journal",

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T1 - Photo-initiated cationic polymerization of cyclohexene oxide using photosensitive polymers having benzoin side-groups in the presence of pyridinium salt

AU - Onen, Aysen

AU - Yagci, Yusuf

PY - 1992/7

Y1 - 1992/7

N2 - The photolysis of poly(benzoin acrylate) at γ > 350 nm leads to polymer-bound free radicals which can be oxidized by pyridinium ions. The resulting ionic species are capable of readily initiating the cationic polymerization of cyclohexene oxide (CHO). Photografting of copolymers containing styrene and benzoin acrylate with CHO gave a crosslinked product.

AB - The photolysis of poly(benzoin acrylate) at γ > 350 nm leads to polymer-bound free radicals which can be oxidized by pyridinium ions. The resulting ionic species are capable of readily initiating the cationic polymerization of cyclohexene oxide (CHO). Photografting of copolymers containing styrene and benzoin acrylate with CHO gave a crosslinked product.

UR - http://www.scopus.com/inward/record.url?scp=0026890772&partnerID=8YFLogxK

U2 - 10.1016/0014-3057(92)90074-C

DO - 10.1016/0014-3057(92)90074-C

M3 - Article

AN - SCOPUS:0026890772

SN - 0014-3057

VL - 28

SP - 721

EP - 723

JO - European Polymer Journal

JF - European Polymer Journal

IS - 7

ER -

Photo-initiated cationic polymerization of cyclohexene oxide using photosensitive polymers having benzoin side-groups in the presence of pyridinium salt

Abstract

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