Phenolic Naphthoxazines as Curing Promoters for Benzoxazines

Gizem Kaya; Baris Kiskan; Yusuf Yagci

doi:10.1021/acs.macromol.8b00218

Phenolic Naphthoxazines as Curing Promoters for Benzoxazines

Gizem Kaya, Baris Kiskan^*, Yusuf Yagci

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

69 Citations (Scopus)

Abstract

The effect of phenolic hydroxyl bearing naphthoxazines as catalysts for the ring-opening polymerization (ROP) of simple 1,3-benzoxazines was investigated. The latent catalytic role of napthoxazines in the curing process of the mixtures was demonstrated by DSC and FT-IR investigations. It was found that phenolic naphthoxazines cause clear reduction in ROP temperature, particularly when electron-withdrawing groups are attached and an onset ROP temperature as low as 169 °C is attained. Thermal properties of the final polymers were also analyzed, and no significant effect of naphthoxazines on the thermal stability of the cured polybenzoxazines was observed.

Original language	English
Pages (from-to)	1688-1695
Number of pages	8
Journal	Macromolecules
Volume	51
Issue number	5
DOIs	https://doi.org/10.1021/acs.macromol.8b00218
Publication status	Published - 13 Mar 2018

Bibliographical note

Publisher Copyright:
© 2018 American Chemical Society.

Access to Document

10.1021/acs.macromol.8b00218

Cite this

@article{f8827f648a1549c8a582df6217f33873,

title = "Phenolic Naphthoxazines as Curing Promoters for Benzoxazines",

abstract = "The effect of phenolic hydroxyl bearing naphthoxazines as catalysts for the ring-opening polymerization (ROP) of simple 1,3-benzoxazines was investigated. The latent catalytic role of napthoxazines in the curing process of the mixtures was demonstrated by DSC and FT-IR investigations. It was found that phenolic naphthoxazines cause clear reduction in ROP temperature, particularly when electron-withdrawing groups are attached and an onset ROP temperature as low as 169 °C is attained. Thermal properties of the final polymers were also analyzed, and no significant effect of naphthoxazines on the thermal stability of the cured polybenzoxazines was observed.",

author = "Gizem Kaya and Baris Kiskan and Yusuf Yagci",

note = "Publisher Copyright: {\textcopyright} 2018 American Chemical Society.",

year = "2018",

month = mar,

day = "13",

doi = "10.1021/acs.macromol.8b00218",

language = "English",

volume = "51",

pages = "1688--1695",

journal = "Macromolecules",

issn = "0024-9297",

publisher = "American Chemical Society",

number = "5",

}

TY - JOUR

T1 - Phenolic Naphthoxazines as Curing Promoters for Benzoxazines

AU - Kaya, Gizem

AU - Kiskan, Baris

AU - Yagci, Yusuf

PY - 2018/3/13

Y1 - 2018/3/13

N2 - The effect of phenolic hydroxyl bearing naphthoxazines as catalysts for the ring-opening polymerization (ROP) of simple 1,3-benzoxazines was investigated. The latent catalytic role of napthoxazines in the curing process of the mixtures was demonstrated by DSC and FT-IR investigations. It was found that phenolic naphthoxazines cause clear reduction in ROP temperature, particularly when electron-withdrawing groups are attached and an onset ROP temperature as low as 169 °C is attained. Thermal properties of the final polymers were also analyzed, and no significant effect of naphthoxazines on the thermal stability of the cured polybenzoxazines was observed.

AB - The effect of phenolic hydroxyl bearing naphthoxazines as catalysts for the ring-opening polymerization (ROP) of simple 1,3-benzoxazines was investigated. The latent catalytic role of napthoxazines in the curing process of the mixtures was demonstrated by DSC and FT-IR investigations. It was found that phenolic naphthoxazines cause clear reduction in ROP temperature, particularly when electron-withdrawing groups are attached and an onset ROP temperature as low as 169 °C is attained. Thermal properties of the final polymers were also analyzed, and no significant effect of naphthoxazines on the thermal stability of the cured polybenzoxazines was observed.

UR - http://www.scopus.com/inward/record.url?scp=85043775362&partnerID=8YFLogxK

U2 - 10.1021/acs.macromol.8b00218

DO - 10.1021/acs.macromol.8b00218

M3 - Article

AN - SCOPUS:85043775362

SN - 0024-9297

VL - 51

SP - 1688

EP - 1695

JO - Macromolecules

JF - Macromolecules

IS - 5

ER -

Phenolic Naphthoxazines as Curing Promoters for Benzoxazines

Abstract

Bibliographical note

Access to Document

Other files and links

Fingerprint

Cite this