Performance of Zn-Schiff Base complex catalyst in NaBH4 hydrolysis reaction

Dilek Kılınç; Ömer Şahin

doi:10.1016/j.ijhydene.2020.07.156

Performance of Zn-Schiff Base complex catalyst in NaBH₄ hydrolysis reaction

Dilek Kılınç^*, Ömer Şahin

^*Corresponding author for this work

Siirt University

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

This study presents 4,4′-methylenebis(2,6-diethyl)aniline-3,5-ditertbutylsalisilaldimine-Zn complex synthesis and its using as a catalyst in sodium borohydride hydrolysis to H₂ generation. Surface morphology and structural properties of Zn-complex were investigated with XRD, FTIR, SEM, and BET analysis. The effects of different substrate concentration, effects of solution temperature, and effects of catalyst amount were studied for the hydrogen generation rate. Additionally kinetic parameters were studied. The activation energy was 22.978 kJ/mol and H₂ generation rates were calculated as 952.5 mmol H₂/g_cat.min and 614.4 mmol H₂/g_cat.min at 50 °C and 30 °C respectively for sodium borohydride hydrolysis reaction.

Original language	English
Pages (from-to)	34783-34792
Number of pages	10
Journal	International Journal of Hydrogen Energy
Volume	45
Issue number	60
DOIs	https://doi.org/10.1016/j.ijhydene.2020.07.156
Publication status	Published - 9 Dec 2020
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2020 Hydrogen Energy Publications LLC

Keywords

Catalyst
Hydrolysis
Schiff base
Sodium borohydride

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1016/j.ijhydene.2020.07.156

Cite this

@article{70281bdc1f5445829c78ec7a5f5e687d,

title = "Performance of Zn-Schiff Base complex catalyst in NaBH4 hydrolysis reaction",

abstract = "This study presents 4,4′-methylenebis(2,6-diethyl)aniline-3,5-ditertbutylsalisilaldimine-Zn complex synthesis and its using as a catalyst in sodium borohydride hydrolysis to H2 generation. Surface morphology and structural properties of Zn-complex were investigated with XRD, FTIR, SEM, and BET analysis. The effects of different substrate concentration, effects of solution temperature, and effects of catalyst amount were studied for the hydrogen generation rate. Additionally kinetic parameters were studied. The activation energy was 22.978 kJ/mol and H2 generation rates were calculated as 952.5 mmol H2/gcat.min and 614.4 mmol H2/gcat.min at 50 °C and 30 °C respectively for sodium borohydride hydrolysis reaction.",

keywords = "Catalyst, Hydrolysis, Schiff base, Sodium borohydride",

author = "Dilek Kılın{\c c} and {\"O}mer {\c S}ahin",

note = "Publisher Copyright: {\textcopyright} 2020 Hydrogen Energy Publications LLC",

year = "2020",

month = dec,

day = "9",

doi = "10.1016/j.ijhydene.2020.07.156",

language = "English",

volume = "45",

pages = "34783--34792",

journal = "International Journal of Hydrogen Energy",

issn = "0360-3199",

publisher = "Elsevier Ltd",

number = "60",

}

TY - JOUR

T1 - Performance of Zn-Schiff Base complex catalyst in NaBH4 hydrolysis reaction

AU - Kılınç, Dilek

AU - Şahin, Ömer

PY - 2020/12/9

Y1 - 2020/12/9

N2 - This study presents 4,4′-methylenebis(2,6-diethyl)aniline-3,5-ditertbutylsalisilaldimine-Zn complex synthesis and its using as a catalyst in sodium borohydride hydrolysis to H2 generation. Surface morphology and structural properties of Zn-complex were investigated with XRD, FTIR, SEM, and BET analysis. The effects of different substrate concentration, effects of solution temperature, and effects of catalyst amount were studied for the hydrogen generation rate. Additionally kinetic parameters were studied. The activation energy was 22.978 kJ/mol and H2 generation rates were calculated as 952.5 mmol H2/gcat.min and 614.4 mmol H2/gcat.min at 50 °C and 30 °C respectively for sodium borohydride hydrolysis reaction.

AB - This study presents 4,4′-methylenebis(2,6-diethyl)aniline-3,5-ditertbutylsalisilaldimine-Zn complex synthesis and its using as a catalyst in sodium borohydride hydrolysis to H2 generation. Surface morphology and structural properties of Zn-complex were investigated with XRD, FTIR, SEM, and BET analysis. The effects of different substrate concentration, effects of solution temperature, and effects of catalyst amount were studied for the hydrogen generation rate. Additionally kinetic parameters were studied. The activation energy was 22.978 kJ/mol and H2 generation rates were calculated as 952.5 mmol H2/gcat.min and 614.4 mmol H2/gcat.min at 50 °C and 30 °C respectively for sodium borohydride hydrolysis reaction.

KW - Catalyst

KW - Hydrolysis

KW - Schiff base

KW - Sodium borohydride

UR - http://www.scopus.com/inward/record.url?scp=85089294589&partnerID=8YFLogxK

U2 - 10.1016/j.ijhydene.2020.07.156

DO - 10.1016/j.ijhydene.2020.07.156

M3 - Article

AN - SCOPUS:85089294589

SN - 0360-3199

VL - 45

SP - 34783

EP - 34792

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

IS - 60

ER -