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Paramagnetic characterization and dosimetric properties of Airfix drug and its ingredients (Montelukast sodium, Sorbitol): An EPR and DFT study

  • Emel Ece*
  • , Halil Ugur Tasdemir
  • , Recep Biyik
  • , Ayhan Ozmen
  • , Ulku Sayin
  • *Corresponding author for this work
  • Karamanoglu Mehmetbey University
  • Selcuk University
  • Necmettin Erbakan University
  • Nuclear Energy Research Institute

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

In this study, radiation effect on an asthma drug Airfix and its ingredients (Montelukast sodium, Sorbitol) were analyzed by using EPR spectroscopy in the dose range of 10 Gy–30 kGy. The dependence of radiation-induced radicals on irradiation dose, temperature and time was investigated in detail. It has been determined that the radical observed predominantly in the Airfix structure originates from Sorbitol, and the characteristic features of this alkyl-type radical have been clearly defined using both experimental EPR and theoretical DFT methods. Dosimetric properties were investigated for all samples and it was suggested that Airfix drug and Sorbitol could be used as an EPR dosimeter through this radical agent which was determined to be very stable and sensitive to radiation. Moreover, it has been emphasized that other drugs containing Sorbitol excipient can also be used for dosimetric purposes in the dose range studied and even irradiation doses can be detected in case of radiation sterilization.

Original languageEnglish
Article number110082
JournalRadiation Physics and Chemistry
Volume195
DOIs
Publication statusPublished - Jun 2022
Externally publishedYes

Bibliographical note

Publisher Copyright:
© 2022

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

  1. SDG 3 - Good Health and Well-being
    SDG 3 Good Health and Well-being

Keywords

  • Alkyl radical
  • Density functional theory (DFT)
  • EPR Dosimetry
  • Montelukast sodium
  • Sorbitol
  • γ-irradiation

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