TY - JOUR
T1 - Oxidative polymerization of N-substituted carbazoles
AU - Saraç, A. Sezai
AU - Sezer, Esma
AU - Ustamehmetoǧlu, Belkis
PY - 1997/9
Y1 - 1997/9
N2 - Poly(N-vinylcarbazole), poly(N-carbazole) and poly(N-ethylcarbazole) powders were chemically synthesized by the reaction of ceric ammonium nitrate (CAN) with N-vinylcarbazole carbazole and N-ethylcarbazole in acetonitrile. Products were characterized by elemental analysis, Fourier transform infrared spectroscopy, scanning electron microscopy and viscosity, X-ray fluorescence and four-probe conductivity measurement. It is found that when a suitable concentration of CAN is used in the polymerization process, the conductivity of chemically synthesized polymers can be improved further by controlling the CAN addition.
AB - Poly(N-vinylcarbazole), poly(N-carbazole) and poly(N-ethylcarbazole) powders were chemically synthesized by the reaction of ceric ammonium nitrate (CAN) with N-vinylcarbazole carbazole and N-ethylcarbazole in acetonitrile. Products were characterized by elemental analysis, Fourier transform infrared spectroscopy, scanning electron microscopy and viscosity, X-ray fluorescence and four-probe conductivity measurement. It is found that when a suitable concentration of CAN is used in the polymerization process, the conductivity of chemically synthesized polymers can be improved further by controlling the CAN addition.
KW - Carbazole
KW - Ceric ammonium nitrate
KW - Conductive polycarbazoles
KW - N-ethylcarbazole
KW - N-vinylcarbazole
KW - Oxidative polymerization
UR - http://www.scopus.com/inward/record.url?scp=0031238081&partnerID=8YFLogxK
U2 - 10.1002/(SICI)1099-1581(199709)8:9<556::AID-PAT686>3.0.CO;2-L
DO - 10.1002/(SICI)1099-1581(199709)8:9<556::AID-PAT686>3.0.CO;2-L
M3 - Article
AN - SCOPUS:0031238081
SN - 1042-7147
VL - 8
SP - 556
EP - 562
JO - Polymers for Advanced Technologies
JF - Polymers for Advanced Technologies
IS - 9
ER -