Oxidative copolymerization of pyrrole and N-methyl pyrrole

Belkis Ustamehmetoǧlu; Eda Kelleboz; A. Sezai Saraç

doi:10.1080/10236660304882

Oxidative copolymerization of pyrrole and N-methyl pyrrole

Belkis Ustamehmetoǧlu^*
, Eda Kelleboz
, A. Sezai Saraç

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

Pyrrole and N-methyl pyrrole were copolymerized by ceric ammonium nitrate (CAN) in aqueous solution. The resulting products were characterized by Fourier-transform infrared spectroscopy, UV-visible spectroscopy, and four-point probe conductivity measurements. The specific electrical conductivity of the copolymers can be increased depending on the mole ratio of pyrrole/N-methylpyrrole. The conductivities of copolymers are in the range of 10^-4-10^-2 S cm^-1. Kinetic parameters were obtained by gravimetric determination of the copolymer and found to be dependent on [pyrrole]^0.87 [N-methyl pyrrole]^0.06 [CAN]^0.11 [H₂SO₄]^1.28 from gravimetric determination.

Original language	English
Pages (from-to)	255-268
Number of pages	14
Journal	International Journal of Polymer Analysis and Characterization
Volume	8
Issue number	4
DOIs	https://doi.org/10.1080/10236660304882
Publication status	Published - Jul 2003

Keywords

Ceric salt
Chemical polymerization
Copolymerization of pyrrole and N-methyl pyrrole

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title = "Oxidative copolymerization of pyrrole and N-methyl pyrrole",

abstract = "Pyrrole and N-methyl pyrrole were copolymerized by ceric ammonium nitrate (CAN) in aqueous solution. The resulting products were characterized by Fourier-transform infrared spectroscopy, UV-visible spectroscopy, and four-point probe conductivity measurements. The specific electrical conductivity of the copolymers can be increased depending on the mole ratio of pyrrole/N-methylpyrrole. The conductivities of copolymers are in the range of 10-4-10-2 S cm-1. Kinetic parameters were obtained by gravimetric determination of the copolymer and found to be dependent on [pyrrole]0.87 [N-methyl pyrrole]0.06 [CAN]0.11 [H2SO4]1.28 from gravimetric determination.",

keywords = "Ceric salt, Chemical polymerization, Copolymerization of pyrrole and N-methyl pyrrole",

author = "Belkis Ustamehmetoǧlu and Eda Kelleboz and Sara{\c c}, \{A. Sezai\}",

year = "2003",

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doi = "10.1080/10236660304882",

language = "English",

volume = "8",

pages = "255--268",

journal = "International Journal of Polymer Analysis and Characterization",

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TY - JOUR

T1 - Oxidative copolymerization of pyrrole and N-methyl pyrrole

AU - Ustamehmetoǧlu, Belkis

AU - Kelleboz, Eda

AU - Saraç, A. Sezai

PY - 2003/7

Y1 - 2003/7

N2 - Pyrrole and N-methyl pyrrole were copolymerized by ceric ammonium nitrate (CAN) in aqueous solution. The resulting products were characterized by Fourier-transform infrared spectroscopy, UV-visible spectroscopy, and four-point probe conductivity measurements. The specific electrical conductivity of the copolymers can be increased depending on the mole ratio of pyrrole/N-methylpyrrole. The conductivities of copolymers are in the range of 10-4-10-2 S cm-1. Kinetic parameters were obtained by gravimetric determination of the copolymer and found to be dependent on [pyrrole]0.87 [N-methyl pyrrole]0.06 [CAN]0.11 [H2SO4]1.28 from gravimetric determination.

AB - Pyrrole and N-methyl pyrrole were copolymerized by ceric ammonium nitrate (CAN) in aqueous solution. The resulting products were characterized by Fourier-transform infrared spectroscopy, UV-visible spectroscopy, and four-point probe conductivity measurements. The specific electrical conductivity of the copolymers can be increased depending on the mole ratio of pyrrole/N-methylpyrrole. The conductivities of copolymers are in the range of 10-4-10-2 S cm-1. Kinetic parameters were obtained by gravimetric determination of the copolymer and found to be dependent on [pyrrole]0.87 [N-methyl pyrrole]0.06 [CAN]0.11 [H2SO4]1.28 from gravimetric determination.

KW - Ceric salt

KW - Chemical polymerization

KW - Copolymerization of pyrrole and N-methyl pyrrole

UR - https://www.scopus.com/pages/publications/0141519113

U2 - 10.1080/10236660304882

DO - 10.1080/10236660304882

M3 - Article

AN - SCOPUS:0141519113

SN - 1023-666X

VL - 8

SP - 255

EP - 268

JO - International Journal of Polymer Analysis and Characterization

JF - International Journal of Polymer Analysis and Characterization

IS - 4

ER -

Oxidative copolymerization of pyrrole and N-methyl pyrrole

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Keywords

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