Origin of structural instability in TlInS2(1-x)Se2x solid solutions

Mirhasan Yu Seyidov*, Rauf A. Suleymanov, Ferid Salehli

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

14 Citations (Scopus)

Abstract

The influence of the isovalent substitution of selenium for sulfur in the anion sublattice of mixed TlInS2(1-x)Se2x crystals has been studied by means of dielectric measurements. It is shown that transformations in the In4(SxSe1-x) 10 structural unit must be taken into account considering the nature of possible phase transitions in TlInS2(1-x)Se2 solid solutions. Possible mechanisms of the phase transition including instabilities in the electronic subsystem of pure TlInSe2 crystals are discussed.

Original languageEnglish
Article number015601
JournalPhysica Scripta
Volume84
Issue number1
DOIs
Publication statusPublished - Jul 2011

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