Optical and Morphological Properties of New Metallophthalocyanines with Hydroxyethylsulfanyl Substituents

İdris Sorar; İbrahim Özçeşmeci; Ahmet Gül

doi:10.1134/S2070205119050241

Optical and Morphological Properties of New Metallophthalocyanines with Hydroxyethylsulfanyl Substituents

İdris Sorar^*, İbrahim Özçeşmeci, Ahmet Gül

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Abstract: Metallophthalocyanine complexes (M = Pd, FeCl, VO, or MnCl) bearing four hydroxyl-terminated aliphatic groups were prepared by cyclotetramerization 4-(hydroxyethylsulfanyl)phthalonitrile. Aggregation tendencies of these phthalocyanines were investigated in varying concentrations from 4 × 10^–5 to 8 × 10^–6 M in DMF. Spin coating method was used to prepare thin films of metallophthalocyanines substituted with four hydroxyethylsulfanyl groups. The optical properties of the films were investigated as a function of the different metal ions in the inner core, with the transmittance spectrum measured at a wavelength range of 200–1000 nm. The results show that different metal ions in the inner core clearly change the transmittance values of the thin films of metallophthalocyanine. Morphological results also show that surface of the metallophthalocyanines has changed considerably according to the nature of the metal ion.

Original language	English
Pages (from-to)	1019-1024
Number of pages	6
Journal	Protection of Metals and Physical Chemistry of Surfaces
Volume	55
Issue number	5
DOIs	https://doi.org/10.1134/S2070205119050241
Publication status	Published - 1 Sept 2019

Bibliographical note

Publisher Copyright:
© 2019, Pleiades Publishing, Ltd.

Funding

The Research Fund of Istanbul Technical University was supported this work. AG thanks Turkish Academy of Sciences (TUBA) for partial support.

Funders	Funder number
TUBA
Türkiye Bilimler Akademisi
Istanbul Teknik Üniversitesi

Keywords

hydroxyethylsulfanyl groups
metallophthalocyanine
morphological properties
optical properties
synthesis

Access to Document

10.1134/S2070205119050241

Cite this

@article{a0f47deb53b84fac9904a592b9a7d24c,

title = "Optical and Morphological Properties of New Metallophthalocyanines with Hydroxyethylsulfanyl Substituents",

abstract = "Abstract: Metallophthalocyanine complexes (M = Pd, FeCl, VO, or MnCl) bearing four hydroxyl-terminated aliphatic groups were prepared by cyclotetramerization 4-(hydroxyethylsulfanyl)phthalonitrile. Aggregation tendencies of these phthalocyanines were investigated in varying concentrations from 4 × 10–5 to 8 × 10–6 M in DMF. Spin coating method was used to prepare thin films of metallophthalocyanines substituted with four hydroxyethylsulfanyl groups. The optical properties of the films were investigated as a function of the different metal ions in the inner core, with the transmittance spectrum measured at a wavelength range of 200–1000 nm. The results show that different metal ions in the inner core clearly change the transmittance values of the thin films of metallophthalocyanine. Morphological results also show that surface of the metallophthalocyanines has changed considerably according to the nature of the metal ion.",

keywords = "hydroxyethylsulfanyl groups, metallophthalocyanine, morphological properties, optical properties, synthesis",

author = "İdris Sorar and İbrahim {\"O}z{\c c}e{\c s}meci and Ahmet G{\"u}l",

note = "Publisher Copyright: {\textcopyright} 2019, Pleiades Publishing, Ltd.",

year = "2019",

month = sep,

day = "1",

doi = "10.1134/S2070205119050241",

language = "English",

volume = "55",

pages = "1019--1024",

journal = "Protection of Metals and Physical Chemistry of Surfaces",

issn = "2070-2051",

publisher = "Pleiades Publishing",

number = "5",

}

TY - JOUR

T1 - Optical and Morphological Properties of New Metallophthalocyanines with Hydroxyethylsulfanyl Substituents

AU - Sorar, İdris

AU - Özçeşmeci, İbrahim

AU - Gül, Ahmet

PY - 2019/9/1

Y1 - 2019/9/1

N2 - Abstract: Metallophthalocyanine complexes (M = Pd, FeCl, VO, or MnCl) bearing four hydroxyl-terminated aliphatic groups were prepared by cyclotetramerization 4-(hydroxyethylsulfanyl)phthalonitrile. Aggregation tendencies of these phthalocyanines were investigated in varying concentrations from 4 × 10–5 to 8 × 10–6 M in DMF. Spin coating method was used to prepare thin films of metallophthalocyanines substituted with four hydroxyethylsulfanyl groups. The optical properties of the films were investigated as a function of the different metal ions in the inner core, with the transmittance spectrum measured at a wavelength range of 200–1000 nm. The results show that different metal ions in the inner core clearly change the transmittance values of the thin films of metallophthalocyanine. Morphological results also show that surface of the metallophthalocyanines has changed considerably according to the nature of the metal ion.

AB - Abstract: Metallophthalocyanine complexes (M = Pd, FeCl, VO, or MnCl) bearing four hydroxyl-terminated aliphatic groups were prepared by cyclotetramerization 4-(hydroxyethylsulfanyl)phthalonitrile. Aggregation tendencies of these phthalocyanines were investigated in varying concentrations from 4 × 10–5 to 8 × 10–6 M in DMF. Spin coating method was used to prepare thin films of metallophthalocyanines substituted with four hydroxyethylsulfanyl groups. The optical properties of the films were investigated as a function of the different metal ions in the inner core, with the transmittance spectrum measured at a wavelength range of 200–1000 nm. The results show that different metal ions in the inner core clearly change the transmittance values of the thin films of metallophthalocyanine. Morphological results also show that surface of the metallophthalocyanines has changed considerably according to the nature of the metal ion.

KW - hydroxyethylsulfanyl groups

KW - metallophthalocyanine

KW - morphological properties

KW - optical properties

KW - synthesis

UR - http://www.scopus.com/inward/record.url?scp=85073602471&partnerID=8YFLogxK

U2 - 10.1134/S2070205119050241

DO - 10.1134/S2070205119050241

M3 - Article

AN - SCOPUS:85073602471

SN - 2070-2051

VL - 55

SP - 1019

EP - 1024

JO - Protection of Metals and Physical Chemistry of Surfaces

JF - Protection of Metals and Physical Chemistry of Surfaces

IS - 5

ER -

Optical and Morphological Properties of New Metallophthalocyanines with Hydroxyethylsulfanyl Substituents

Abstract

Bibliographical note

Funding

Keywords

Access to Document

Other files and links

Fingerprint

Cite this