One-pot synthesis of poly(triazole-graft-caprolactone) via ring-opening polymerization combined with click chemistry as a novel strategy for graft copolymers

Fusun Seyma Gungor; Baris Kiskan

doi:10.1016/j.reactfunctpolym.2013.12.005

One-pot synthesis of poly(triazole-graft-caprolactone) via ring-opening polymerization combined with click chemistry as a novel strategy for graft copolymers

Fusun Seyma Gungor
, Baris Kiskan^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

The one-pot construction of polytriazole grafted with poly(ε- caprolactone) via the polymerization of 4-azido-1-(prop-2-yn-1-yloxy)butan-2-ol (N₃hydroxypropargyl) and ε-caprolactone monomers is reported. For this purpose, a click reaction and ring-opening polymerization (ROP) were combined and carried out simultaneously. N₃hydroxypropargyl served as both the ROP initiator and a monomer for the click polymerization. Thus, an in situ "grafting-through and from" strategy was established in one pot. CuBr and Sn(Oct)₂ were utilized as dual catalysts, and the polymerization reactions were carried out at 120 C under a N₂ atmosphere.

Original language	English
Pages (from-to)	51-55
Number of pages	5
Journal	Reactive and Functional Polymers
Volume	75
Issue number	1
DOIs	https://doi.org/10.1016/j.reactfunctpolym.2013.12.005
Publication status	Published - Feb 2014

Funding

The authors thank to Istanbul Technical University Research Fund for financial support (Project No. 36167 ) and Prof. Dr. Yusuf Yagci for providing infrastructure.

Funders	Funder number
Istanbul Teknik Üniversitesi	36167

Keywords

Click chemistry
Graft copolymer
One-pot synthesis
Poly(ε-caprolactone)
Polytriazole

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10.1016/j.reactfunctpolym.2013.12.005

Cite this

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title = "One-pot synthesis of poly(triazole-graft-caprolactone) via ring-opening polymerization combined with click chemistry as a novel strategy for graft copolymers",

abstract = "The one-pot construction of polytriazole grafted with poly(ε- caprolactone) via the polymerization of 4-azido-1-(prop-2-yn-1-yloxy)butan-2-ol (N3hydroxypropargyl) and ε-caprolactone monomers is reported. For this purpose, a click reaction and ring-opening polymerization (ROP) were combined and carried out simultaneously. N3hydroxypropargyl served as both the ROP initiator and a monomer for the click polymerization. Thus, an in situ {"}grafting-through and from{"} strategy was established in one pot. CuBr and Sn(Oct)2 were utilized as dual catalysts, and the polymerization reactions were carried out at 120 C under a N2 atmosphere.",

keywords = "Click chemistry, Graft copolymer, One-pot synthesis, Poly(ε-caprolactone), Polytriazole",

author = "Gungor, \{Fusun Seyma\} and Baris Kiskan",

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doi = "10.1016/j.reactfunctpolym.2013.12.005",

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journal = "Reactive and Functional Polymers",

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T1 - One-pot synthesis of poly(triazole-graft-caprolactone) via ring-opening polymerization combined with click chemistry as a novel strategy for graft copolymers

AU - Gungor, Fusun Seyma

AU - Kiskan, Baris

PY - 2014/2

Y1 - 2014/2

N2 - The one-pot construction of polytriazole grafted with poly(ε- caprolactone) via the polymerization of 4-azido-1-(prop-2-yn-1-yloxy)butan-2-ol (N3hydroxypropargyl) and ε-caprolactone monomers is reported. For this purpose, a click reaction and ring-opening polymerization (ROP) were combined and carried out simultaneously. N3hydroxypropargyl served as both the ROP initiator and a monomer for the click polymerization. Thus, an in situ "grafting-through and from" strategy was established in one pot. CuBr and Sn(Oct)2 were utilized as dual catalysts, and the polymerization reactions were carried out at 120 C under a N2 atmosphere.

AB - The one-pot construction of polytriazole grafted with poly(ε- caprolactone) via the polymerization of 4-azido-1-(prop-2-yn-1-yloxy)butan-2-ol (N3hydroxypropargyl) and ε-caprolactone monomers is reported. For this purpose, a click reaction and ring-opening polymerization (ROP) were combined and carried out simultaneously. N3hydroxypropargyl served as both the ROP initiator and a monomer for the click polymerization. Thus, an in situ "grafting-through and from" strategy was established in one pot. CuBr and Sn(Oct)2 were utilized as dual catalysts, and the polymerization reactions were carried out at 120 C under a N2 atmosphere.

KW - Click chemistry

KW - Graft copolymer

KW - One-pot synthesis

KW - Poly(ε-caprolactone)

KW - Polytriazole

UR - https://www.scopus.com/pages/publications/84891750344

U2 - 10.1016/j.reactfunctpolym.2013.12.005

DO - 10.1016/j.reactfunctpolym.2013.12.005

M3 - Article

AN - SCOPUS:84891750344

SN - 1381-5148

VL - 75

SP - 51

EP - 55

JO - Reactive and Functional Polymers

JF - Reactive and Functional Polymers

IS - 1

ER -

One-pot synthesis of poly(triazole-graft-caprolactone) via ring-opening polymerization combined with click chemistry as a novel strategy for graft copolymers

Abstract

Funding

Keywords

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