One-Pot, One-Step Strategy for the Preparation of Clickable Melamine Based Microporous Organic Polymer Network

Omer Suat Taskin, Baris Kiskan, Jens Weber, Yusuf Yagci*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

25 Citations (Scopus)

Abstract

Although, current preparation methods for microporous organic polymers (MOP) based on coupling or condensations reactions are simple and flexible, they suffer from the requirement of additional modification steps for introducing properties for specific purposes. In the present work, we have developed a simple and rapid synthetic strategy to prepare MOP possessing reactive sites to incorporate any molecules of interest by "Click Chemistry". The clickable MOP with high surface area was readily synthesized through Schiff base chemistry using propargylated anthraquinone and melamine in the catalyst free, one-pot process. The versatility of the click coupling on the acetylene functional MOP was demonstrated on a model reaction using independently prepared fluorescent azido-pyrene.

Original languageEnglish
Pages (from-to)1116-1122
Number of pages7
JournalMacromolecular Materials and Engineering
Volume300
Issue number11
DOIs
Publication statusPublished - Nov 2015

Bibliographical note

Publisher Copyright:
© 2015 Wiley-VCH Verlag GmbH and Co. KGaA, Weinheim.

Keywords

  • click reaction
  • melamine
  • microporous material
  • post modification
  • Schiff base chemistry

Fingerprint

Dive into the research topics of 'One-Pot, One-Step Strategy for the Preparation of Clickable Melamine Based Microporous Organic Polymer Network'. Together they form a unique fingerprint.

Cite this