Novel phthalocyanines with pentafluorobenzyloxy-substituents

Mukaddes Selçukoǧlu; Esin Hamuryudan

doi:10.1016/j.dyepig.2006.01.009

Novel phthalocyanines with pentafluorobenzyloxy-substituents

Mukaddes Selçukoǧlu, Esin Hamuryudan^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

62 Citations (Scopus)

Abstract

The synthesis of pentafluorobenzyloxy substituted metal-free phthalocyanine 4 was achieved by co-cyclotetramerization of 4-(2′,3′,4′,5′,6′-pentafluorobenzyloxy)phthalonitrile (3) with hydroquinone, whereas metallophthalocyanines (MPcs) 5-7 were synthesized in the presence of zinc, cobalt or nickel salts. The compounds were characterized by their elemental analyses, UV-vis, FT-IR, ¹H NMR, ¹⁹F NMR and mass spectroscopic methods.

Original language	English
Pages (from-to)	17-20
Number of pages	4
Journal	Dyes and Pigments
Volume	74
Issue number	1
DOIs	https://doi.org/10.1016/j.dyepig.2006.01.009
Publication status	Published - 2007

Funding

This work was supported by the Research Fund of the Technical University of Istanbul and State Planning Organisation (DPT).

Funders	Funder number
DPT
Technical University of Istanbul and State Planning Organisation

Keywords

2,3,4,5,6-Pentafluorobenzyl alcohol
Copper
Fluorocarbons
Phthalocyanines
Zinc

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10.1016/j.dyepig.2006.01.009

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abstract = "The synthesis of pentafluorobenzyloxy substituted metal-free phthalocyanine 4 was achieved by co-cyclotetramerization of 4-(2′,3′,4′,5′,6′-pentafluorobenzyloxy)phthalonitrile (3) with hydroquinone, whereas metallophthalocyanines (MPcs) 5-7 were synthesized in the presence of zinc, cobalt or nickel salts. The compounds were characterized by their elemental analyses, UV-vis, FT-IR, 1H NMR, 19F NMR and mass spectroscopic methods.",

keywords = "2,3,4,5,6-Pentafluorobenzyl alcohol, Copper, Fluorocarbons, Phthalocyanines, Zinc",

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AU - Selçukoǧlu, Mukaddes

AU - Hamuryudan, Esin

PY - 2007

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N2 - The synthesis of pentafluorobenzyloxy substituted metal-free phthalocyanine 4 was achieved by co-cyclotetramerization of 4-(2′,3′,4′,5′,6′-pentafluorobenzyloxy)phthalonitrile (3) with hydroquinone, whereas metallophthalocyanines (MPcs) 5-7 were synthesized in the presence of zinc, cobalt or nickel salts. The compounds were characterized by their elemental analyses, UV-vis, FT-IR, 1H NMR, 19F NMR and mass spectroscopic methods.

AB - The synthesis of pentafluorobenzyloxy substituted metal-free phthalocyanine 4 was achieved by co-cyclotetramerization of 4-(2′,3′,4′,5′,6′-pentafluorobenzyloxy)phthalonitrile (3) with hydroquinone, whereas metallophthalocyanines (MPcs) 5-7 were synthesized in the presence of zinc, cobalt or nickel salts. The compounds were characterized by their elemental analyses, UV-vis, FT-IR, 1H NMR, 19F NMR and mass spectroscopic methods.

KW - 2,3,4,5,6-Pentafluorobenzyl alcohol

KW - Copper

KW - Fluorocarbons

KW - Phthalocyanines

KW - Zinc

UR - https://www.scopus.com/pages/publications/33751248524

U2 - 10.1016/j.dyepig.2006.01.009

DO - 10.1016/j.dyepig.2006.01.009

M3 - Article

AN - SCOPUS:33751248524

SN - 0143-7208

VL - 74

SP - 17

EP - 20

JO - Dyes and Pigments

JF - Dyes and Pigments

IS - 1

ER -

Novel phthalocyanines with pentafluorobenzyloxy-substituents

Abstract

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Keywords

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