Novel lead acid battery paste recycling process

M. S. Sonmez*, V. P. Kotzeva, R. V. Kumar

*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

1 Citation (Scopus)

Abstract

In this study experimental conditions were expressed for a new process of recycling lead paste at relatively lower temperatures. Lead acid battery paste was reacted with the mixture of citric acid, sodium citrate and hydrogen peroxide solution in this process. The solution mixture provided the removal of sulphur content of the paste as well as the decomposition of lead dioxide. Complete transformation to lead citrate was achieved by experimenting hydrometallurgical conditions of leaching-crystallisation step. Then thermal behaviour of lead citrate was investigated accordingly. Lead citrate crystals were decomposed to lead oxide at around 300°C without any addition. Direct reduction of lead from lead citrate was also possible under specific conditions. Experimental results reflected the efficient recovery of spent lead acid battery pastes without the use of high temperature pyrometallurgy or energy intensive electrolysis techniques.

Original languageEnglish
Title of host publicationPb Zn 2010 - Lead-Zinc 2010 Symposium, Held in Conjunction with COM 2010
Pages111-117
Number of pages7
Publication statusPublished - 2010
Event5th Lead-Zinc Symposium, Pb Zn 2010, Held in Conjunction with COM 2010 - Vancouver, BC, Canada
Duration: 3 Oct 20106 Oct 2010

Publication series

NamePb Zn 2010 - Lead-Zinc 2010 Symposium, Held in Conjunction with COM 2010

Conference

Conference5th Lead-Zinc Symposium, Pb Zn 2010, Held in Conjunction with COM 2010
Country/TerritoryCanada
CityVancouver, BC
Period3/10/106/10/10

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