New photoinitiating systems for cationic polymerization acting at near UV and visible range

Binnur Aydogan; Yasemin Yuksel Durmaz; Muhammet U. Kahveci; Mustafa Uygun; M. Atilla Tasdelen; Yusuf Yagci

doi:10.1002/masy.201151005

New photoinitiating systems for cationic polymerization acting at near UV and visible range

Binnur Aydogan, Yasemin Yuksel Durmaz, Muhammet U. Kahveci, Mustafa Uygun, M. Atilla Tasdelen, Yusuf Yagci^*

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

New photoiniting systems for cationic polymerization acting at near UV and visible range are described. The applicability of acylgermanes as a new class of free radical promoters for photoinitiated cationic polymerization is demonstrated. Moreover, the use of substituted vinyl halides as source for readily oxidizable free radicals is presented. The polymerization of vinyl ethers can be initiated by the irradiation of substituted vinyl halides in the presence of Lewis acids such as zinc halide. Furthermore, possibilities for conducting cationic polymerization at visible range by using highly conjugated thiophene derivatives are demonstrated. Mechanistic aspects of all initiating systems are discussed.

Original language	English
Pages (from-to)	25-34
Number of pages	10
Journal	Macromolecular Symposia
Volume	308
Issue number	1
DOIs	https://doi.org/10.1002/masy.201151005
Publication status	Published - Oct 2011

Keywords

acyl german
cationic polymerization
dithienothiophene
photopolymerization
vinyl halides

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abstract = "New photoiniting systems for cationic polymerization acting at near UV and visible range are described. The applicability of acylgermanes as a new class of free radical promoters for photoinitiated cationic polymerization is demonstrated. Moreover, the use of substituted vinyl halides as source for readily oxidizable free radicals is presented. The polymerization of vinyl ethers can be initiated by the irradiation of substituted vinyl halides in the presence of Lewis acids such as zinc halide. Furthermore, possibilities for conducting cationic polymerization at visible range by using highly conjugated thiophene derivatives are demonstrated. Mechanistic aspects of all initiating systems are discussed.",

keywords = "acyl german, cationic polymerization, dithienothiophene, photopolymerization, vinyl halides",

author = "Binnur Aydogan and Durmaz, {Yasemin Yuksel} and Kahveci, {Muhammet U.} and Mustafa Uygun and Tasdelen, {M. Atilla} and Yusuf Yagci",

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AU - Aydogan, Binnur

AU - Durmaz, Yasemin Yuksel

AU - Kahveci, Muhammet U.

AU - Uygun, Mustafa

AU - Tasdelen, M. Atilla

AU - Yagci, Yusuf

PY - 2011/10

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N2 - New photoiniting systems for cationic polymerization acting at near UV and visible range are described. The applicability of acylgermanes as a new class of free radical promoters for photoinitiated cationic polymerization is demonstrated. Moreover, the use of substituted vinyl halides as source for readily oxidizable free radicals is presented. The polymerization of vinyl ethers can be initiated by the irradiation of substituted vinyl halides in the presence of Lewis acids such as zinc halide. Furthermore, possibilities for conducting cationic polymerization at visible range by using highly conjugated thiophene derivatives are demonstrated. Mechanistic aspects of all initiating systems are discussed.

AB - New photoiniting systems for cationic polymerization acting at near UV and visible range are described. The applicability of acylgermanes as a new class of free radical promoters for photoinitiated cationic polymerization is demonstrated. Moreover, the use of substituted vinyl halides as source for readily oxidizable free radicals is presented. The polymerization of vinyl ethers can be initiated by the irradiation of substituted vinyl halides in the presence of Lewis acids such as zinc halide. Furthermore, possibilities for conducting cationic polymerization at visible range by using highly conjugated thiophene derivatives are demonstrated. Mechanistic aspects of all initiating systems are discussed.

KW - acyl german

KW - cationic polymerization

KW - dithienothiophene

KW - photopolymerization

KW - vinyl halides

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JO - Macromolecular Symposia

JF - Macromolecular Symposia

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New photoinitiating systems for cationic polymerization acting at near UV and visible range

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