Monomer reactivity ratios of itaconic acid and acrylamide copolymers determined by using potentiometric titration method

Nurseli Uyanik; Candan Erbil

doi:10.1016/S0014-3057(00)00045-8

Monomer reactivity ratios of itaconic acid and acrylamide copolymers determined by using potentiometric titration method

Nurseli Uyanik
, Candan Erbil

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

Itaconic acid (methylene succinic acid)-acrylamide (IA-AAm) copolymers were synthesized with solution polymerization by using potassium persulphate. The potentiometric titration method was used to determine the copolymer compositions. The results were evaluated by various methods. The monomer reactivity ratios were found to be r_IA = 0.99±0.04, r_AAm = 0.58±0.02 with the Fineman-Ross, r_IA = 1.05±0.10, r_AAm = 0.62±0.06 with the Kelen-Tudos, and r_IA = 1.36±0.11, r_AAm = 0.77±0.06 with the Tidwell-Mortimer methods. As expected, IA is found to be the more reactive monomer in IA-AAm copolymers.

Original language	English
Pages (from-to)	2651-2654
Number of pages	4
Journal	European Polymer Journal
Volume	36
Issue number	12
DOIs	https://doi.org/10.1016/S0014-3057(00)00045-8
Publication status	Published - Dec 2000

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title = "Monomer reactivity ratios of itaconic acid and acrylamide copolymers determined by using potentiometric titration method",

abstract = "Itaconic acid (methylene succinic acid)-acrylamide (IA-AAm) copolymers were synthesized with solution polymerization by using potassium persulphate. The potentiometric titration method was used to determine the copolymer compositions. The results were evaluated by various methods. The monomer reactivity ratios were found to be rIA = 0.99±0.04, rAAm = 0.58±0.02 with the Fineman-Ross, rIA = 1.05±0.10, rAAm = 0.62±0.06 with the Kelen-Tudos, and rIA = 1.36±0.11, rAAm = 0.77±0.06 with the Tidwell-Mortimer methods. As expected, IA is found to be the more reactive monomer in IA-AAm copolymers.",

author = "Nurseli Uyanik and Candan Erbil",

year = "2000",

month = dec,

doi = "10.1016/S0014-3057(00)00045-8",

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journal = "European Polymer Journal",

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T1 - Monomer reactivity ratios of itaconic acid and acrylamide copolymers determined by using potentiometric titration method

AU - Uyanik, Nurseli

AU - Erbil, Candan

PY - 2000/12

Y1 - 2000/12

N2 - Itaconic acid (methylene succinic acid)-acrylamide (IA-AAm) copolymers were synthesized with solution polymerization by using potassium persulphate. The potentiometric titration method was used to determine the copolymer compositions. The results were evaluated by various methods. The monomer reactivity ratios were found to be rIA = 0.99±0.04, rAAm = 0.58±0.02 with the Fineman-Ross, rIA = 1.05±0.10, rAAm = 0.62±0.06 with the Kelen-Tudos, and rIA = 1.36±0.11, rAAm = 0.77±0.06 with the Tidwell-Mortimer methods. As expected, IA is found to be the more reactive monomer in IA-AAm copolymers.

AB - Itaconic acid (methylene succinic acid)-acrylamide (IA-AAm) copolymers were synthesized with solution polymerization by using potassium persulphate. The potentiometric titration method was used to determine the copolymer compositions. The results were evaluated by various methods. The monomer reactivity ratios were found to be rIA = 0.99±0.04, rAAm = 0.58±0.02 with the Fineman-Ross, rIA = 1.05±0.10, rAAm = 0.62±0.06 with the Kelen-Tudos, and rIA = 1.36±0.11, rAAm = 0.77±0.06 with the Tidwell-Mortimer methods. As expected, IA is found to be the more reactive monomer in IA-AAm copolymers.

UR - https://www.scopus.com/pages/publications/0033672061

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DO - 10.1016/S0014-3057(00)00045-8

M3 - Article

AN - SCOPUS:0033672061

SN - 0014-3057

VL - 36

SP - 2651

EP - 2654

JO - European Polymer Journal

JF - European Polymer Journal

IS - 12

ER -

Monomer reactivity ratios of itaconic acid and acrylamide copolymers determined by using potentiometric titration method

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