Microstructural morphologies of slag based glass-ceramics nucleated with 5 wt% Cr2O3 and 5 wt% Cr2O3 + 5 wt% TiO2

M. L. Öveçoǧlu; E. Çatakli; Z. E. Erkmen; B. Özkal

Microstructural morphologies of slag based glass-ceramics nucleated with 5 wt% Cr₂O₃ and 5 wt% Cr₂O₃ + 5 wt% TiO₂

M. L. Öveçoǧlu^*, E. Çatakli, Z. E. Erkmen, B. Özkal

^*Corresponding author for this work

Department of Metallurgical and Materials Engineering

Istanbul Technical University

Research output: Contribution to journal › Conference article › peer-review

1 Citation (Scopus)

Abstract

Glass-ceramic materials were developed from the blast-furnace slags by mixing 5 wt% Cr₂O₃ and 5 wt% Cr₂O₃ + 5 wt% TiO₂. The samples were nucleated for 18 h at 780 °C and crystallized for 20 min. at 905 °C, respectively. SEM and SEM/EDS investigations revealed the presence of clover-shaped TiO₂ particles in the glassy matrix of the sample nucleated with 5 wt% Cr₂O₃ + 5 wt% TiO₂ and polygonal-shaped Cr₂O₃ platelets for both samples. XRD scans revealed the presence of akermanite (2CaO.MgO.2SiO₂) and gehlenite (2CaO.Al₂O₃.SiO₂) peaks indicating the existence of the mellilite solid solution for the crystallized glass-ceramic samples.

Original language	English
Pages (from-to)	863-866
Number of pages	4
Journal	Key Engineering Materials
Volume	206-213
Issue number	II
Publication status	Published - 2001
Event	7th Conference and Exhibition of the European Ceramic Society - Brugge, Belgium Duration: 9 Sept 2001 → 13 Sept 2001

Keywords

CrO
Slag based glass-ceramics
TiO nucleants

Cite this

@article{9450021ee28e403ca5f668ccb6a9f328,

title = "Microstructural morphologies of slag based glass-ceramics nucleated with 5 wt% Cr2O3 and 5 wt% Cr2O3 + 5 wt% TiO2",

abstract = "Glass-ceramic materials were developed from the blast-furnace slags by mixing 5 wt% Cr2O3 and 5 wt% Cr2O3 + 5 wt% TiO2. The samples were nucleated for 18 h at 780 °C and crystallized for 20 min. at 905 °C, respectively. SEM and SEM/EDS investigations revealed the presence of clover-shaped TiO2 particles in the glassy matrix of the sample nucleated with 5 wt% Cr2O3 + 5 wt% TiO2 and polygonal-shaped Cr2O3 platelets for both samples. XRD scans revealed the presence of akermanite (2CaO.MgO.2SiO2) and gehlenite (2CaO.Al2O3.SiO2) peaks indicating the existence of the mellilite solid solution for the crystallized glass-ceramic samples.",

keywords = "CrO, Slag based glass-ceramics, TiO nucleants",

author = "{\"O}ve{\c c}oǧlu, {M. L.} and E. {\c C}atakli and Erkmen, {Z. E.} and B. {\"O}zkal",

year = "2001",

language = "English",

volume = "206-213",

pages = "863--866",

journal = "Key Engineering Materials",

issn = "1013-9826",

publisher = "Trans Tech Publications",

number = "II",

note = "7th Conference and Exhibition of the European Ceramic Society ; Conference date: 09-09-2001 Through 13-09-2001",

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TY - JOUR

T1 - Microstructural morphologies of slag based glass-ceramics nucleated with 5 wt% Cr2O3 and 5 wt% Cr2O3 + 5 wt% TiO2

AU - Öveçoǧlu, M. L.

AU - Çatakli, E.

AU - Erkmen, Z. E.

AU - Özkal, B.

PY - 2001

Y1 - 2001

N2 - Glass-ceramic materials were developed from the blast-furnace slags by mixing 5 wt% Cr2O3 and 5 wt% Cr2O3 + 5 wt% TiO2. The samples were nucleated for 18 h at 780 °C and crystallized for 20 min. at 905 °C, respectively. SEM and SEM/EDS investigations revealed the presence of clover-shaped TiO2 particles in the glassy matrix of the sample nucleated with 5 wt% Cr2O3 + 5 wt% TiO2 and polygonal-shaped Cr2O3 platelets for both samples. XRD scans revealed the presence of akermanite (2CaO.MgO.2SiO2) and gehlenite (2CaO.Al2O3.SiO2) peaks indicating the existence of the mellilite solid solution for the crystallized glass-ceramic samples.

AB - Glass-ceramic materials were developed from the blast-furnace slags by mixing 5 wt% Cr2O3 and 5 wt% Cr2O3 + 5 wt% TiO2. The samples were nucleated for 18 h at 780 °C and crystallized for 20 min. at 905 °C, respectively. SEM and SEM/EDS investigations revealed the presence of clover-shaped TiO2 particles in the glassy matrix of the sample nucleated with 5 wt% Cr2O3 + 5 wt% TiO2 and polygonal-shaped Cr2O3 platelets for both samples. XRD scans revealed the presence of akermanite (2CaO.MgO.2SiO2) and gehlenite (2CaO.Al2O3.SiO2) peaks indicating the existence of the mellilite solid solution for the crystallized glass-ceramic samples.

KW - CrO

KW - Slag based glass-ceramics

KW - TiO nucleants

UR - http://www.scopus.com/inward/record.url?scp=0034782575&partnerID=8YFLogxK

M3 - Conference article

AN - SCOPUS:0034782575

SN - 1013-9826

VL - 206-213

SP - 863

EP - 866

JO - Key Engineering Materials

JF - Key Engineering Materials

IS - II

T2 - 7th Conference and Exhibition of the European Ceramic Society

Y2 - 9 September 2001 through 13 September 2001

ER -

Microstructural morphologies of slag based glass-ceramics nucleated with 5 wt% Cr₂O₃ and 5 wt% Cr₂O₃ + 5 wt% TiO₂

Abstract

Keywords

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