Metallophthalocyanines with rod-shaped substituents

Ayfer Kalkan; Ayşe Aytekin; Zehra Altuntaş Bayır

doi:10.1007/s11243-006-0053-x

Metallophthalocyanines with rod-shaped substituents

Ayfer Kalkan, Ayşe Aytekin, Zehra Altuntaş Bayır^*

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

4-(4′-Dioctylaminocarbonylbiphenyloxy) phthalonitrile was synthesized from 4-(4′-carboxybiphenyloxy)phthalonitrile and dioctylamine in the presence of Et ₃ N. Metallophthalocyanines (Zn, Co and Cu) substituted with four dioctylaminocarbonyl biphenyloxy groups on the peripheral positions were prepared from 4-(4′-dioctylaminocarbonylbiphenyloxy)phthalonitrile and the corresponding divalent metal salts (Zn(CH ₃ COO) ₂ , CoCl ₂ and CuCl ₂ ). The new phthalocyanines are soluble in common organic solvents. These compounds were characterised by ¹ H-NMR, ¹³ C-NMR, FT-IR, UV-Vis and mass spectroscopies.

Original language	English
Pages (from-to)	720-723
Number of pages	4
Journal	Transition Metal Chemistry
Volume	31
Issue number	6
DOIs	https://doi.org/10.1007/s11243-006-0053-x
Publication status	Published - Sept 2006

Funding

This work was supported by the Research Fund of the Technical University of Istanbul and TÜBÏTAK-TBAG.

Funders	Funder number
TÜBÏTAK-TBAG
Istanbul Teknik Üniversitesi

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title = "Metallophthalocyanines with rod-shaped substituents",

abstract = " 4-(4′-Dioctylaminocarbonylbiphenyloxy) phthalonitrile was synthesized from 4-(4′-carboxybiphenyloxy)phthalonitrile and dioctylamine in the presence of Et 3 N. Metallophthalocyanines (Zn, Co and Cu) substituted with four dioctylaminocarbonyl biphenyloxy groups on the peripheral positions were prepared from 4-(4′-dioctylaminocarbonylbiphenyloxy)phthalonitrile and the corresponding divalent metal salts (Zn(CH 3 COO) 2 , CoCl 2 and CuCl 2 ). The new phthalocyanines are soluble in common organic solvents. These compounds were characterised by 1 H-NMR, 13 C-NMR, FT-IR, UV-Vis and mass spectroscopies.",

author = "Ayfer Kalkan and Ay{\c s}e Aytekin and Bayır, \{Zehra Altunta{\c s}\}",

year = "2006",

month = sep,

doi = "10.1007/s11243-006-0053-x",

language = "English",

volume = "31",

pages = "720--723",

journal = "Transition Metal Chemistry",

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T1 - Metallophthalocyanines with rod-shaped substituents

AU - Kalkan, Ayfer

AU - Aytekin, Ayşe

AU - Bayır, Zehra Altuntaş

PY - 2006/9

Y1 - 2006/9

N2 - 4-(4′-Dioctylaminocarbonylbiphenyloxy) phthalonitrile was synthesized from 4-(4′-carboxybiphenyloxy)phthalonitrile and dioctylamine in the presence of Et 3 N. Metallophthalocyanines (Zn, Co and Cu) substituted with four dioctylaminocarbonyl biphenyloxy groups on the peripheral positions were prepared from 4-(4′-dioctylaminocarbonylbiphenyloxy)phthalonitrile and the corresponding divalent metal salts (Zn(CH 3 COO) 2 , CoCl 2 and CuCl 2 ). The new phthalocyanines are soluble in common organic solvents. These compounds were characterised by 1 H-NMR, 13 C-NMR, FT-IR, UV-Vis and mass spectroscopies.

AB - 4-(4′-Dioctylaminocarbonylbiphenyloxy) phthalonitrile was synthesized from 4-(4′-carboxybiphenyloxy)phthalonitrile and dioctylamine in the presence of Et 3 N. Metallophthalocyanines (Zn, Co and Cu) substituted with four dioctylaminocarbonyl biphenyloxy groups on the peripheral positions were prepared from 4-(4′-dioctylaminocarbonylbiphenyloxy)phthalonitrile and the corresponding divalent metal salts (Zn(CH 3 COO) 2 , CoCl 2 and CuCl 2 ). The new phthalocyanines are soluble in common organic solvents. These compounds were characterised by 1 H-NMR, 13 C-NMR, FT-IR, UV-Vis and mass spectroscopies.

UR - https://www.scopus.com/pages/publications/33748342365

U2 - 10.1007/s11243-006-0053-x

DO - 10.1007/s11243-006-0053-x

M3 - Article

AN - SCOPUS:33748342365

SN - 0340-4285

VL - 31

SP - 720

EP - 723

JO - Transition Metal Chemistry

JF - Transition Metal Chemistry

IS - 6

ER -

Metallophthalocyanines with rod-shaped substituents

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