TY - JOUR
T1 - Metallophthalocyanines with rod-shaped substituents
AU - Kalkan, Ayfer
AU - Aytekin, Ayşe
AU - Bayır, Zehra Altuntaş
PY - 2006/9
Y1 - 2006/9
N2 - 4-(4′-Dioctylaminocarbonylbiphenyloxy) phthalonitrile was synthesized from 4-(4′-carboxybiphenyloxy)phthalonitrile and dioctylamine in the presence of Et 3 N. Metallophthalocyanines (Zn, Co and Cu) substituted with four dioctylaminocarbonyl biphenyloxy groups on the peripheral positions were prepared from 4-(4′-dioctylaminocarbonylbiphenyloxy)phthalonitrile and the corresponding divalent metal salts (Zn(CH 3 COO) 2 , CoCl 2 and CuCl 2 ). The new phthalocyanines are soluble in common organic solvents. These compounds were characterised by 1 H-NMR, 13 C-NMR, FT-IR, UV-Vis and mass spectroscopies.
AB - 4-(4′-Dioctylaminocarbonylbiphenyloxy) phthalonitrile was synthesized from 4-(4′-carboxybiphenyloxy)phthalonitrile and dioctylamine in the presence of Et 3 N. Metallophthalocyanines (Zn, Co and Cu) substituted with four dioctylaminocarbonyl biphenyloxy groups on the peripheral positions were prepared from 4-(4′-dioctylaminocarbonylbiphenyloxy)phthalonitrile and the corresponding divalent metal salts (Zn(CH 3 COO) 2 , CoCl 2 and CuCl 2 ). The new phthalocyanines are soluble in common organic solvents. These compounds were characterised by 1 H-NMR, 13 C-NMR, FT-IR, UV-Vis and mass spectroscopies.
UR - http://www.scopus.com/inward/record.url?scp=33748342365&partnerID=8YFLogxK
U2 - 10.1007/s11243-006-0053-x
DO - 10.1007/s11243-006-0053-x
M3 - Article
AN - SCOPUS:33748342365
SN - 0340-4285
VL - 31
SP - 720
EP - 723
JO - Transition Metal Chemistry
JF - Transition Metal Chemistry
IS - 6
ER -