Abstract
The high temperature batch and continuous pyrolysis of rice husk, sewage sludge, composite waste, hazelnut and apricot kernel shell were performed at 850 °C in a rotating batch reactor and a continuous reactor with a modified ribbon screw conveyor. Batch results were used in the continuous reactor design and comparison. At the continuous pyrolysis experiments, mixing and conveying efficiency of screw and thermal cracking performance of reactor, heated gas line and cyclone were investigated. Each material was fed into the reactor continuously with a feed rate of 4.5 kg/h for 3.5 h, and then the pipelines and reactor were monitored and collected tar and char were analyzed. The mixing unit and uninterrupted heated system showed excellent performance on tar reduction and tar yields were lower than 1.7 % for all materials. Separation of char dust from the gas without tar condensation in a heated cyclone prevented blocking in gas lines. With the secondary reactions syngas energy conversion efficiency for rice husk, sewage sludge, composite waste, hazelnut shell, and apricot kernel shell were 67.76 %, 59.22 %, 76.35 %, 56.96 %, 61.98 % respectively. With the new design with a modified ribbon screw, different types of materials were decomposed with minimum char yield in less than 15 min without mechanical problems. The high capacity of the installed reactor as 1–10 kg/h moved the technology readiness level (TRL) to 5 and set an example for demonstration in operational environment.
Original language | English |
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Pages (from-to) | 1332-1343 |
Number of pages | 12 |
Journal | International Journal of Hydrogen Energy |
Volume | 53 |
DOIs | |
Publication status | Published - 31 Jan 2024 |
Bibliographical note
Publisher Copyright:© 2023 Hydrogen Energy Publications LLC
Funding
This work made use of Synthetic Fuels and Chemicals Technology Center Facilities at Istanbul Technical University. The authors would like to express their appreciation and gratitude to Presidency of the Republic of Turkey Strategy and Budget Presidency for providing the funding of ITU Synthetic Fuels and Chemicals Technology Center Project (grant number 2016K121250). This work made use of Synthetic Fuels and Chemicals Technology Center Facilities at Istanbul Technical University. The authors would like to express their appreciation and gratitude to Presidency of the Republic of Turkey Strategy and Budget Presidency for providing the funding of ITU Synthetic Fuels and Chemicals Technology Center Project (grant number 2016K121250 ).
Funders | Funder number |
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International Technological University | 2016K121250 |
Istanbul Teknik Üniversitesi |
Keywords
- Continuous pyrolysis
- High-temperature pyrolysis
- Low tar
- Screw reactor
- Thermal cracking