Living and controlled polymerization of isobutylene with Alkylaluminum halides as coinitiators

Savvas Hadjikyriacou; Metin Acar; Rudolf Faust

doi:10.1021/ma049082s

Living and controlled polymerization of isobutylene with Alkylaluminum halides as coinitiators

Savvas Hadjikyriacou
, Metin Acar
, Rudolf Faust^*

^*Corresponding author for this work

University of Massachusetts Lowell

Research output: Contribution to journal › Article › peer-review

41 Citations (Scopus)

Abstract

The living polymerization of isobutylene (IB) coinitiated by methylaluminum chlorides was investigated. The investigation was performed in hexanes solvent mixture at -80 °C in the presence and absence of a proton trap. The polymerization was found to be slower in the presence of the sample proton trap. The results show that at higher concentrations the polymerization is uncontroled due to the extremely rapid polymerization.

Original language	English
Pages (from-to)	7543-7547
Number of pages	5
Journal	Macromolecules
Volume	37
Issue number	20
DOIs	https://doi.org/10.1021/ma049082s
Publication status	Published - 5 Oct 2004
Externally published	Yes

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10.1021/ma049082s

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title = "Living and controlled polymerization of isobutylene with Alkylaluminum halides as coinitiators",

abstract = "The living polymerization of isobutylene (IB) coinitiated by methylaluminum chlorides was investigated. The investigation was performed in hexanes solvent mixture at -80 °C in the presence and absence of a proton trap. The polymerization was found to be slower in the presence of the sample proton trap. The results show that at higher concentrations the polymerization is uncontroled due to the extremely rapid polymerization.",

author = "Savvas Hadjikyriacou and Metin Acar and Rudolf Faust",

year = "2004",

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doi = "10.1021/ma049082s",

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T1 - Living and controlled polymerization of isobutylene with Alkylaluminum halides as coinitiators

AU - Hadjikyriacou, Savvas

AU - Acar, Metin

AU - Faust, Rudolf

PY - 2004/10/5

Y1 - 2004/10/5

N2 - The living polymerization of isobutylene (IB) coinitiated by methylaluminum chlorides was investigated. The investigation was performed in hexanes solvent mixture at -80 °C in the presence and absence of a proton trap. The polymerization was found to be slower in the presence of the sample proton trap. The results show that at higher concentrations the polymerization is uncontroled due to the extremely rapid polymerization.

AB - The living polymerization of isobutylene (IB) coinitiated by methylaluminum chlorides was investigated. The investigation was performed in hexanes solvent mixture at -80 °C in the presence and absence of a proton trap. The polymerization was found to be slower in the presence of the sample proton trap. The results show that at higher concentrations the polymerization is uncontroled due to the extremely rapid polymerization.

UR - https://www.scopus.com/pages/publications/6344284981

U2 - 10.1021/ma049082s

DO - 10.1021/ma049082s

M3 - Article

AN - SCOPUS:6344284981

SN - 0024-9297

VL - 37

SP - 7543

EP - 7547

JO - Macromolecules

JF - Macromolecules

IS - 20

ER -

Living and controlled polymerization of isobutylene with Alkylaluminum halides as coinitiators

Abstract

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