Liquid state 15N NMR studies of 15N isotope labeled phthalocyanines

Armaʇan Atsay; Ahmet Gül; Makbule Burkut Koçak

doi:10.3906/kim-1506-8

Liquid state ¹⁵N NMR studies of ¹⁵N isotope labeled phthalocyanines

Armaʇan Atsay, Ahmet Gül, Makbule Burkut Koçak^*

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

¹⁵N labeled soluble metallo- and metal-free phthalocyanines are described for the first time. The complexes were synthesized starting from phthalic anhydride derivatives using 98% ¹⁵N enriched urea. The effects of the substitution pattern, aggregation, and coordinated metal on ¹⁵N chemical shifts in liquid state NMR were studied.

Original language	English
Pages (from-to)	163-173
Number of pages	11
Journal	Turkish Journal of Chemistry
Volume	40
Issue number	1
DOIs	https://doi.org/10.3906/kim-1506-8
Publication status	Published - 2016

Bibliographical note

Publisher Copyright:
© 2016 TÜB̄TAK.

Keywords

N NMR
Constitutional isomers
Isotopic shifts
Phthalocyanines

Access to Document

10.3906/kim-1506-8

Cite this

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abstract = "15N labeled soluble metallo- and metal-free phthalocyanines are described for the first time. The complexes were synthesized starting from phthalic anhydride derivatives using 98% 15N enriched urea. The effects of the substitution pattern, aggregation, and coordinated metal on 15N chemical shifts in liquid state NMR were studied.",

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AB - 15N labeled soluble metallo- and metal-free phthalocyanines are described for the first time. The complexes were synthesized starting from phthalic anhydride derivatives using 98% 15N enriched urea. The effects of the substitution pattern, aggregation, and coordinated metal on 15N chemical shifts in liquid state NMR were studied.

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