Lateral variation of the native passive film on super duplex stainless steel resolved by synchrotron hard X-ray photoelectron emission microscopy

M. Långberg; F. Zhang; E. Grånäs; C. Örnek; J. Cheng; M. Liu; C. Wiemann; A. Gloskovskii; T. F. Keller; C. Schlueter; S. Kulkarni; H. Noei; D. Lindell; U. Kivisäkk; E. Lundgren; A. Stierle; J. Pan

doi:10.1016/j.corsci.2020.108841

Lateral variation of the native passive film on super duplex stainless steel resolved by synchrotron hard X-ray photoelectron emission microscopy

M. Långberg
, F. Zhang
, E. Grånäs
, C. Örnek
, J. Cheng
, M. Liu
, C. Wiemann
, A. Gloskovskii
, T. F. Keller
, C. Schlueter
, S. Kulkarni
, H. Noei
, D. Lindell
, U. Kivisäkk
, E. Lundgren
, A. Stierle
, J. Pan^*

^*Corresponding author for this work

Department of Metallurgical and Materials Engineering

KTH Royal Institute of Technology
Swerim AB
German Electron Synchrotron
Jülich Research Centre
University of Hamburg
Sandvik AB
Lund University

Research output: Contribution to journal › Article › peer-review

33 Citations (Scopus)

Abstract

A native passive film on 25Cr-7Ni super duplex stainless steel was analyzed using synchrotron hard X-ray photoemission electron microscopy, focusing on variations between individual grains of ferrite and austenite phases. The film consists of an oxide inner layer and an oxyhydroxide outer layer, in total 2.3 nm thick. The Cr content is higher in the outer than the inner layer, ca. 80 % on average. The Cr content is higher on ferrite than austenite, whereas the thickness is rather uniform. The grain orientation has a small but detectable influence, ferrite (111) grains have a lower Cr content than other ferrite grains.

Original language	English
Article number	108841
Journal	Corrosion Science
Volume	174
DOIs	https://doi.org/10.1016/j.corsci.2020.108841
Publication status	Published - Sept 2020

Bibliographical note

Publisher Copyright:
© 2020 The Authors

Keywords

duplex stainless steel
lateral variation
passive film
photoelectron emission spectroscopy
synchrotron technique

Access to Document

10.1016/j.corsci.2020.108841

Cite this

Långberg, M., Zhang, F., Grånäs, E., Örnek, C., Cheng, J., Liu, M., Wiemann, C., Gloskovskii, A., Keller, T. F., Schlueter, C., Kulkarni, S., Noei, H., Lindell, D., Kivisäkk, U., Lundgren, E., Stierle, A., & Pan, J. (2020). Lateral variation of the native passive film on super duplex stainless steel resolved by synchrotron hard X-ray photoelectron emission microscopy. Corrosion Science, 174, Article 108841. https://doi.org/10.1016/j.corsci.2020.108841

@article{98f4dad8aa574f8a91731afc0cda90cd,

title = "Lateral variation of the native passive film on super duplex stainless steel resolved by synchrotron hard X-ray photoelectron emission microscopy",

abstract = "A native passive film on 25Cr-7Ni super duplex stainless steel was analyzed using synchrotron hard X-ray photoemission electron microscopy, focusing on variations between individual grains of ferrite and austenite phases. The film consists of an oxide inner layer and an oxyhydroxide outer layer, in total 2.3 nm thick. The Cr content is higher in the outer than the inner layer, ca. 80 \% on average. The Cr content is higher on ferrite than austenite, whereas the thickness is rather uniform. The grain orientation has a small but detectable influence, ferrite (111) grains have a lower Cr content than other ferrite grains.",

keywords = "duplex stainless steel, lateral variation, passive film, photoelectron emission spectroscopy, synchrotron technique",

author = "M. L{\aa}ngberg and F. Zhang and E. Gr{\aa}n{\"a}s and C. {\"O}rnek and J. Cheng and M. Liu and C. Wiemann and A. Gloskovskii and Keller, \{T. F.\} and C. Schlueter and S. Kulkarni and H. Noei and D. Lindell and U. Kivis{\"a}kk and E. Lundgren and A. Stierle and J. Pan",

note = "Publisher Copyright: {\textcopyright} 2020 The Authors",

year = "2020",

month = sep,

doi = "10.1016/j.corsci.2020.108841",

language = "English",

volume = "174",

journal = "Corrosion Science",

issn = "0010-938X",

publisher = "Elsevier Ltd",

}

Långberg, M, Zhang, F, Grånäs, E, Örnek, C, Cheng, J, Liu, M, Wiemann, C, Gloskovskii, A, Keller, TF, Schlueter, C, Kulkarni, S, Noei, H, Lindell, D, Kivisäkk, U, Lundgren, E, Stierle, A & Pan, J 2020, 'Lateral variation of the native passive film on super duplex stainless steel resolved by synchrotron hard X-ray photoelectron emission microscopy', Corrosion Science, vol. 174, 108841. https://doi.org/10.1016/j.corsci.2020.108841

TY - JOUR

T1 - Lateral variation of the native passive film on super duplex stainless steel resolved by synchrotron hard X-ray photoelectron emission microscopy

AU - Långberg, M.

AU - Zhang, F.

AU - Grånäs, E.

AU - Örnek, C.

AU - Cheng, J.

AU - Liu, M.

AU - Wiemann, C.

AU - Gloskovskii, A.

AU - Keller, T. F.

AU - Schlueter, C.

AU - Kulkarni, S.

AU - Noei, H.

AU - Lindell, D.

AU - Kivisäkk, U.

AU - Lundgren, E.

AU - Stierle, A.

AU - Pan, J.

PY - 2020/9

Y1 - 2020/9

N2 - A native passive film on 25Cr-7Ni super duplex stainless steel was analyzed using synchrotron hard X-ray photoemission electron microscopy, focusing on variations between individual grains of ferrite and austenite phases. The film consists of an oxide inner layer and an oxyhydroxide outer layer, in total 2.3 nm thick. The Cr content is higher in the outer than the inner layer, ca. 80 % on average. The Cr content is higher on ferrite than austenite, whereas the thickness is rather uniform. The grain orientation has a small but detectable influence, ferrite (111) grains have a lower Cr content than other ferrite grains.

AB - A native passive film on 25Cr-7Ni super duplex stainless steel was analyzed using synchrotron hard X-ray photoemission electron microscopy, focusing on variations between individual grains of ferrite and austenite phases. The film consists of an oxide inner layer and an oxyhydroxide outer layer, in total 2.3 nm thick. The Cr content is higher in the outer than the inner layer, ca. 80 % on average. The Cr content is higher on ferrite than austenite, whereas the thickness is rather uniform. The grain orientation has a small but detectable influence, ferrite (111) grains have a lower Cr content than other ferrite grains.

KW - duplex stainless steel

KW - lateral variation

KW - passive film

KW - photoelectron emission spectroscopy

KW - synchrotron technique

UR - https://www.scopus.com/pages/publications/85087508713

U2 - 10.1016/j.corsci.2020.108841

DO - 10.1016/j.corsci.2020.108841

M3 - Article

AN - SCOPUS:85087508713

SN - 0010-938X

VL - 174

JO - Corrosion Science

JF - Corrosion Science

M1 - 108841

ER -

Lateral variation of the native passive film on super duplex stainless steel resolved by synchrotron hard X-ray photoelectron emission microscopy

Abstract

Bibliographical note

Keywords

Access to Document

Other files and links

Fingerprint

Cite this