Kinetic study of photocatalytic decolorization of C.I. Basic Blue 3 solution on immobilized titanium dioxide nanoparticles

A. R. Khataee; M. Fathinia; S. Aber

doi:10.1016/j.cherd.2011.01.001

Kinetic study of photocatalytic decolorization of C.I. Basic Blue 3 solution on immobilized titanium dioxide nanoparticles

A. R. Khataee^*, M. Fathinia, S. Aber

^*Corresponding author for this work

University of Tabriz

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

The photocatalytic decolorization of C.I. Basic Blue 3 (BB3) solution on immobilized TiO₂ nanoparticles was carried out in a rectangular flat-plate photoreactor. The investigated TiO₂ was Millennium PC-500 (anatase, average crystallite size 8nm, surface area 320.76m²g^-1) immobilized on non-woven paper. A new kinetic model was proposed on the basis of intrinsic element reactions. The proposed kinetic model fairly resembled the classic Langmuir-Hinshelwood (L-H) equation from its expression. It was found that both k_obs (the reaction rate constant) and K_R (the adsorption rate constant) were linearly proportional to the light intensity in a rather large intensity range.

Original language	English
Pages (from-to)	2110-2116
Number of pages	7
Journal	Chemical Engineering Research and Design
Volume	89
Issue number	10
DOIs	https://doi.org/10.1016/j.cherd.2011.01.001
Publication status	Published - Oct 2011
Externally published	Yes

Keywords

C.I. Basic Blue 3
Kinetic modeling
Photocatalysis
TiO nanoparticles

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10.1016/j.cherd.2011.01.001

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title = "Kinetic study of photocatalytic decolorization of C.I. Basic Blue 3 solution on immobilized titanium dioxide nanoparticles",

abstract = "The photocatalytic decolorization of C.I. Basic Blue 3 (BB3) solution on immobilized TiO2 nanoparticles was carried out in a rectangular flat-plate photoreactor. The investigated TiO2 was Millennium PC-500 (anatase, average crystallite size 8nm, surface area 320.76m2g-1) immobilized on non-woven paper. A new kinetic model was proposed on the basis of intrinsic element reactions. The proposed kinetic model fairly resembled the classic Langmuir-Hinshelwood (L-H) equation from its expression. It was found that both kobs (the reaction rate constant) and KR (the adsorption rate constant) were linearly proportional to the light intensity in a rather large intensity range.",

keywords = "C.I. Basic Blue 3, Kinetic modeling, Photocatalysis, TiO nanoparticles",

author = "Khataee, \{A. R.\} and M. Fathinia and S. Aber",

year = "2011",

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doi = "10.1016/j.cherd.2011.01.001",

language = "English",

volume = "89",

pages = "2110--2116",

journal = "Chemical Engineering Research and Design",

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T1 - Kinetic study of photocatalytic decolorization of C.I. Basic Blue 3 solution on immobilized titanium dioxide nanoparticles

AU - Khataee, A. R.

AU - Fathinia, M.

AU - Aber, S.

PY - 2011/10

Y1 - 2011/10

N2 - The photocatalytic decolorization of C.I. Basic Blue 3 (BB3) solution on immobilized TiO2 nanoparticles was carried out in a rectangular flat-plate photoreactor. The investigated TiO2 was Millennium PC-500 (anatase, average crystallite size 8nm, surface area 320.76m2g-1) immobilized on non-woven paper. A new kinetic model was proposed on the basis of intrinsic element reactions. The proposed kinetic model fairly resembled the classic Langmuir-Hinshelwood (L-H) equation from its expression. It was found that both kobs (the reaction rate constant) and KR (the adsorption rate constant) were linearly proportional to the light intensity in a rather large intensity range.

AB - The photocatalytic decolorization of C.I. Basic Blue 3 (BB3) solution on immobilized TiO2 nanoparticles was carried out in a rectangular flat-plate photoreactor. The investigated TiO2 was Millennium PC-500 (anatase, average crystallite size 8nm, surface area 320.76m2g-1) immobilized on non-woven paper. A new kinetic model was proposed on the basis of intrinsic element reactions. The proposed kinetic model fairly resembled the classic Langmuir-Hinshelwood (L-H) equation from its expression. It was found that both kobs (the reaction rate constant) and KR (the adsorption rate constant) were linearly proportional to the light intensity in a rather large intensity range.

KW - C.I. Basic Blue 3

KW - Kinetic modeling

KW - Photocatalysis

KW - TiO nanoparticles

UR - https://www.scopus.com/pages/publications/80052796252

U2 - 10.1016/j.cherd.2011.01.001

DO - 10.1016/j.cherd.2011.01.001

M3 - Article

AN - SCOPUS:80052796252

SN - 0263-8762

VL - 89

SP - 2110

EP - 2116

JO - Chemical Engineering Research and Design

JF - Chemical Engineering Research and Design

IS - 10

ER -

Kinetic study of photocatalytic decolorization of C.I. Basic Blue 3 solution on immobilized titanium dioxide nanoparticles

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