Investigation of high catalytic activity catalyst for high hydrogen production rate: Co-Ru@MOF

Erhan Onat; Sabri Çevik; Ömer Şahin; Sabit Horoz; Mehmet Sait İzgi

doi:10.1007/s41779-021-00643-9

Investigation of high catalytic activity catalyst for high hydrogen production rate: Co-Ru@MOF

Erhan Onat
, Sabri Çevik
, Ömer Şahin
, Sabit Horoz
, Mehmet Sait İzgi^*

^*Corresponding author for this work

Siirt University
Afyon Kocatepe University

Research output: Contribution to journal › Article › peer-review

35 Citations (Scopus)

Abstract

We report the synthesis of metal–organic framework supported-Co-Ru (Co-Ru@MOF) catalyst and its catalytic activity. The synthesized Co-Ru@MOF catalyst for the first time is used to obtain the maximum hydrogen production rate from hydrolysis of NaBH₄. The synthesized Co-Ru@MOF catalyst indicates a compelling performance in the hydrogen production from the hydrolysis of NaBH₄. It is found that Co-Ru@MOF with the loading of Co (80 wt%) and Ru (20 wt%) indicates a high hydrogen production rate of 15,144 mL/min.g and low activation energy of 41.41 kJ mol⁻¹. The current study demonstrates that MOF is promising support for dispersing metal catalysts. Moreover, the synthesized Co-Ru@MOF catalyst is characterized by x-ray diffraction (XRD), scanning electron microscope (SEM), and energy dispersion spectroscopy (EDS) measurements.

Original language	English
Pages (from-to)	1389-1395
Number of pages	7
Journal	Journal of the Australian Ceramic Society
Volume	57
Issue number	5
DOIs	https://doi.org/10.1007/s41779-021-00643-9
Publication status	Published - Dec 2021
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2021, Australian Ceramic Society.

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Catalyst
Hydrogen
NaBH
Support material

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10.1007/s41779-021-00643-9

Cite this

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title = "Investigation of high catalytic activity catalyst for high hydrogen production rate: Co-Ru@MOF",

abstract = "We report the synthesis of metal–organic framework supported-Co-Ru (Co-Ru@MOF) catalyst and its catalytic activity. The synthesized Co-Ru@MOF catalyst for the first time is used to obtain the maximum hydrogen production rate from hydrolysis of NaBH4. The synthesized Co-Ru@MOF catalyst indicates a compelling performance in the hydrogen production from the hydrolysis of NaBH4. It is found that Co-Ru@MOF with the loading of Co (80 wt\%) and Ru (20 wt\%) indicates a high hydrogen production rate of 15,144 mL/min.g and low activation energy of 41.41 kJ mol−1. The current study demonstrates that MOF is promising support for dispersing metal catalysts. Moreover, the synthesized Co-Ru@MOF catalyst is characterized by x-ray diffraction (XRD), scanning electron microscope (SEM), and energy dispersion spectroscopy (EDS) measurements.",

keywords = "Catalyst, Hydrogen, NaBH, Support material",

author = "Erhan Onat and Sabri {\c C}evik and {\"O}mer {\c S}ahin and Sabit Horoz and İzgi, \{Mehmet Sait\}",

note = "Publisher Copyright: {\textcopyright} 2021, Australian Ceramic Society.",

year = "2021",

month = dec,

doi = "10.1007/s41779-021-00643-9",

language = "English",

volume = "57",

pages = "1389--1395",

journal = "Journal of the Australian Ceramic Society",

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T1 - Investigation of high catalytic activity catalyst for high hydrogen production rate

T2 - Co-Ru@MOF

AU - Onat, Erhan

AU - Çevik, Sabri

AU - Şahin, Ömer

AU - Horoz, Sabit

AU - İzgi, Mehmet Sait

PY - 2021/12

Y1 - 2021/12

N2 - We report the synthesis of metal–organic framework supported-Co-Ru (Co-Ru@MOF) catalyst and its catalytic activity. The synthesized Co-Ru@MOF catalyst for the first time is used to obtain the maximum hydrogen production rate from hydrolysis of NaBH4. The synthesized Co-Ru@MOF catalyst indicates a compelling performance in the hydrogen production from the hydrolysis of NaBH4. It is found that Co-Ru@MOF with the loading of Co (80 wt%) and Ru (20 wt%) indicates a high hydrogen production rate of 15,144 mL/min.g and low activation energy of 41.41 kJ mol−1. The current study demonstrates that MOF is promising support for dispersing metal catalysts. Moreover, the synthesized Co-Ru@MOF catalyst is characterized by x-ray diffraction (XRD), scanning electron microscope (SEM), and energy dispersion spectroscopy (EDS) measurements.

AB - We report the synthesis of metal–organic framework supported-Co-Ru (Co-Ru@MOF) catalyst and its catalytic activity. The synthesized Co-Ru@MOF catalyst for the first time is used to obtain the maximum hydrogen production rate from hydrolysis of NaBH4. The synthesized Co-Ru@MOF catalyst indicates a compelling performance in the hydrogen production from the hydrolysis of NaBH4. It is found that Co-Ru@MOF with the loading of Co (80 wt%) and Ru (20 wt%) indicates a high hydrogen production rate of 15,144 mL/min.g and low activation energy of 41.41 kJ mol−1. The current study demonstrates that MOF is promising support for dispersing metal catalysts. Moreover, the synthesized Co-Ru@MOF catalyst is characterized by x-ray diffraction (XRD), scanning electron microscope (SEM), and energy dispersion spectroscopy (EDS) measurements.

KW - Catalyst

KW - Hydrogen

KW - NaBH

KW - Support material

UR - https://www.scopus.com/pages/publications/85112430170

U2 - 10.1007/s41779-021-00643-9

DO - 10.1007/s41779-021-00643-9

M3 - Article

AN - SCOPUS:85112430170

SN - 2510-1560

VL - 57

SP - 1389

EP - 1395

JO - Journal of the Australian Ceramic Society

JF - Journal of the Australian Ceramic Society

IS - 5

ER -

Investigation of high catalytic activity catalyst for high hydrogen production rate: Co-Ru@MOF

Abstract

Bibliographical note

UN SDGs

Keywords

Access to Document

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