TY - JOUR
T1 - Influence of type of zinc salts on photoinitiated living cationic polymerization of vinyl ethers
AU - Kahveci, Muhammet U.
AU - Oytun, Faruk
AU - Yagci, Yusuf
PY - 2013/8/16
Y1 - 2013/8/16
N2 - Activities of a series of zinc salts in Lewis-acid-mediated cationic photopolymerization of vinyl ethers have been studied. Readily soluble zinc salts including zinc stearate, zinc acetate and zinc oxide; zinc iodide; and metallic zinc were employed as a Lewis acid in propagation stage of the cationic polymerization initiated by photolysis of a substituted vinyl halide, 1-bromo-1,2,2-tris(p-methoxyphenyl)ethene (AAAVB). As a model monomer isobutyl vinyl ether (IBVE) was polymerized by the described system in the presence of the zinc salts or metallic zinc for investigation of efficiencies of the Lewis acids. Novel system containing organo-zinc compounds yielded polymers in more controlled manner. For further evaluation of potential living character of the system, polymerization of IBVE catalyzed by zinc stearate was monitored, and as a result, the polymerization showed quasi-living nature. Activity of the catalyst system in photo-induced crosslinking of difunctional vinyl ether was evaluated as well.
AB - Activities of a series of zinc salts in Lewis-acid-mediated cationic photopolymerization of vinyl ethers have been studied. Readily soluble zinc salts including zinc stearate, zinc acetate and zinc oxide; zinc iodide; and metallic zinc were employed as a Lewis acid in propagation stage of the cationic polymerization initiated by photolysis of a substituted vinyl halide, 1-bromo-1,2,2-tris(p-methoxyphenyl)ethene (AAAVB). As a model monomer isobutyl vinyl ether (IBVE) was polymerized by the described system in the presence of the zinc salts or metallic zinc for investigation of efficiencies of the Lewis acids. Novel system containing organo-zinc compounds yielded polymers in more controlled manner. For further evaluation of potential living character of the system, polymerization of IBVE catalyzed by zinc stearate was monitored, and as a result, the polymerization showed quasi-living nature. Activity of the catalyst system in photo-induced crosslinking of difunctional vinyl ether was evaluated as well.
KW - Cationic polymerization
KW - Living polymerization
KW - Photopolymerization
UR - http://www.scopus.com/inward/record.url?scp=84881546804&partnerID=8YFLogxK
U2 - 10.1016/j.polymer.2013.07.037
DO - 10.1016/j.polymer.2013.07.037
M3 - Article
AN - SCOPUS:84881546804
SN - 0032-3861
VL - 54
SP - 4798
EP - 4801
JO - Polymer
JF - Polymer
IS - 18
ER -