INEPT NMR Spectroscopy of 14NDn groups: Product operator theory and simulation

Deniz Türkpence; Irfan Şaka; Azmi Gençten

doi:10.3906/fiz-1003-20

INEPT NMR Spectroscopy of ¹⁴ND_n groups: Product operator theory and simulation

Deniz Türkpence^*, Irfan Şaka, Azmi Gençten

^*Corresponding author for this work

Ondokuz Mayis University

Research output: Contribution to journal › Article › peer-review

Abstract

Product operator formalism is widely used for the analytical description of multi-dimensional and multiple-pulse NMR experiments for the weakly coupled spin systems having spin-1/2 and spin-1 nuclei. The INEPT NMR experiment is a polarization transfer experiment including J-coupling. In this study, the INEPT NMR experiment was analytically investigated by using product operator theory for weakly coupled IS_n (14ND_n)(I=1, S =1; n=1, 2, 3) spin systems. The obtained theoretical results represent the FID values of 14 ND _n groups. In order to make Fourier transform of the obtained FID values, a Maple program is used and then simulated spectra of the INEPT experiment are obtained for 14 ND_n groups. Then, the experimental suggestions are made for the INEPT NMR experiment of 14 ND_n groups. Also, it is suggested that the INEPT NMR experiment of IS (I=1, S=1) spin system can be used in NMR quantum computing.

Original language	English
Pages (from-to)	139-148
Number of pages	10
Journal	Turkish Journal of Physics
Volume	34
Issue number	3
DOIs	https://doi.org/10.3906/fiz-1003-20
Publication status	Published - 2010
Externally published	Yes

Keywords

INEPT
NMR
Product operator formalism
Spin-1

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10.3906/fiz-1003-20

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title = "INEPT NMR Spectroscopy of 14NDn groups: Product operator theory and simulation",

abstract = "Product operator formalism is widely used for the analytical description of multi-dimensional and multiple-pulse NMR experiments for the weakly coupled spin systems having spin-1/2 and spin-1 nuclei. The INEPT NMR experiment is a polarization transfer experiment including J-coupling. In this study, the INEPT NMR experiment was analytically investigated by using product operator theory for weakly coupled ISn (14NDn)(I=1, S =1; n=1, 2, 3) spin systems. The obtained theoretical results represent the FID values of 14 ND n groups. In order to make Fourier transform of the obtained FID values, a Maple program is used and then simulated spectra of the INEPT experiment are obtained for 14 NDn groups. Then, the experimental suggestions are made for the INEPT NMR experiment of 14 NDn groups. Also, it is suggested that the INEPT NMR experiment of IS (I=1, S=1) spin system can be used in NMR quantum computing.",

keywords = "INEPT, NMR, Product operator formalism, Spin-1",

author = "Deniz T{\"u}rkpence and Irfan {\c S}aka and Azmi Gen{\c c}ten",

year = "2010",

doi = "10.3906/fiz-1003-20",

language = "English",

volume = "34",

pages = "139--148",

journal = "Turkish Journal of Physics",

issn = "1300-0101",

publisher = "TUBITAK",

number = "3",

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TY - JOUR

T1 - INEPT NMR Spectroscopy of 14NDn groups

T2 - Product operator theory and simulation

AU - Türkpence, Deniz

AU - Şaka, Irfan

AU - Gençten, Azmi

PY - 2010

Y1 - 2010

N2 - Product operator formalism is widely used for the analytical description of multi-dimensional and multiple-pulse NMR experiments for the weakly coupled spin systems having spin-1/2 and spin-1 nuclei. The INEPT NMR experiment is a polarization transfer experiment including J-coupling. In this study, the INEPT NMR experiment was analytically investigated by using product operator theory for weakly coupled ISn (14NDn)(I=1, S =1; n=1, 2, 3) spin systems. The obtained theoretical results represent the FID values of 14 ND n groups. In order to make Fourier transform of the obtained FID values, a Maple program is used and then simulated spectra of the INEPT experiment are obtained for 14 NDn groups. Then, the experimental suggestions are made for the INEPT NMR experiment of 14 NDn groups. Also, it is suggested that the INEPT NMR experiment of IS (I=1, S=1) spin system can be used in NMR quantum computing.

AB - Product operator formalism is widely used for the analytical description of multi-dimensional and multiple-pulse NMR experiments for the weakly coupled spin systems having spin-1/2 and spin-1 nuclei. The INEPT NMR experiment is a polarization transfer experiment including J-coupling. In this study, the INEPT NMR experiment was analytically investigated by using product operator theory for weakly coupled ISn (14NDn)(I=1, S =1; n=1, 2, 3) spin systems. The obtained theoretical results represent the FID values of 14 ND n groups. In order to make Fourier transform of the obtained FID values, a Maple program is used and then simulated spectra of the INEPT experiment are obtained for 14 NDn groups. Then, the experimental suggestions are made for the INEPT NMR experiment of 14 NDn groups. Also, it is suggested that the INEPT NMR experiment of IS (I=1, S=1) spin system can be used in NMR quantum computing.

KW - INEPT

KW - NMR

KW - Product operator formalism

KW - Spin-1

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DO - 10.3906/fiz-1003-20

M3 - Article

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VL - 34

SP - 139

EP - 148

JO - Turkish Journal of Physics

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IS - 3

ER -

INEPT NMR Spectroscopy of ¹⁴ND_n groups: Product operator theory and simulation

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Keywords

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