Abstract
The surface properties of discarded glass cutting scissors were improved by modifying their surfaces via a fast, low-cost, and environmentally friendly boron diffusion technique called as cathodic reduction and thermal diffusion-based boriding (CRTD-Bor) process. The kinetic calculations revealed the activation energy of boride growth on discarded AISI T1 steel as 179 kJ/mole. XRD analyses demonstrated the existence of iron borides along with previously formed carbides and the cross-sectional SEM investigations with EDS analyses confirmed these multiple borides and carbide structures. Phase homogenization (PH) stages were integrated into CRTD-Bor to eliminate the brittle FeB layer. After the optimizations, it was achieved to grow ~ 24 µm thick Fe2B layer, exhibiting 1700 ± 200 HV hardness with good adhesion (HF1) to the substrate following to 60 min of treatment (15 min CRTD-Bor and 45 min PH at 900 °C). The idealized boriding procedure improved the oxidation resistance of the discarded T1 steels by tenfold. Graphical abstract: [Figure not available: see fulltext.]
Original language | English |
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Pages (from-to) | 9504-9514 |
Number of pages | 11 |
Journal | Journal of Materials Engineering and Performance |
Volume | 32 |
Issue number | 21 |
DOIs | |
Publication status | Published - Nov 2023 |
Bibliographical note
Publisher Copyright:© 2023, ASM International.
Keywords
- AISI T1
- CRTD-Bor
- boriding
- growth kinetic
- phase homogenization (PH)
- thermal oxidation