Hydrogen Production by Hydrolysis of NaBH4 with Cr-Ni-W-B Catalyst: Effects of Cold Plasma and Chromium Content

Ömer Şahin; Cafer Saka; Arzu Ekinci; Aslm Balbay

doi:10.1515/ijcre-2015-0139

Hydrogen Production by Hydrolysis of NaBH₄ with Cr-Ni-W-B Catalyst: Effects of Cold Plasma and Chromium Content

Ömer Şahin, Cafer Saka^*, Arzu Ekinci, Aslm Balbay

^*Corresponding author for this work

Siirt University

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

In this study, the hydrogen generation from the hydrolysis of NaBH₄ with Cr_0.0125-Ni-W-B catalyst prepared in the presence of cold plasma was investigated based on Cr content, NaBH₄ concentration, NaOH concentration, temperature, plasma applying time and plasma gases effects. The results of the activity tests indicate that the choice of Cr and the catalyst composition greatly influenced the activity as well as the selectivity for hydrogen generation from the hydrolysis of NaBH_4. The Cr_0.0125-Ni-W-B catalyst was treated with argon, nitrogen and carbon dioxide plasma at different treatment times. The catalysts were characterized using SEM, BET surface area measurement and XRD.

Original language	English
Pages (from-to)	351-359
Number of pages	9
Journal	International Journal of Chemical Reactor Engineering
Volume	14
Issue number	1
DOIs	https://doi.org/10.1515/ijcre-2015-0139
Publication status	Published - 1 Feb 2016
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2016 by De Gruyter 2016.

Keywords

cold plasma
Cr-Ni-W-B
hydrogen generation
sodium borohydride

Access to Document

10.1515/ijcre-2015-0139

Cite this

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title = "Hydrogen Production by Hydrolysis of NaBH4 with Cr-Ni-W-B Catalyst: Effects of Cold Plasma and Chromium Content",

abstract = "In this study, the hydrogen generation from the hydrolysis of NaBH4 with Cr0.0125-Ni-W-B catalyst prepared in the presence of cold plasma was investigated based on Cr content, NaBH4 concentration, NaOH concentration, temperature, plasma applying time and plasma gases effects. The results of the activity tests indicate that the choice of Cr and the catalyst composition greatly influenced the activity as well as the selectivity for hydrogen generation from the hydrolysis of NaBH4. The Cr0.0125-Ni-W-B catalyst was treated with argon, nitrogen and carbon dioxide plasma at different treatment times. The catalysts were characterized using SEM, BET surface area measurement and XRD.",

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AU - Ekinci, Arzu

AU - Balbay, Aslm

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AB - In this study, the hydrogen generation from the hydrolysis of NaBH4 with Cr0.0125-Ni-W-B catalyst prepared in the presence of cold plasma was investigated based on Cr content, NaBH4 concentration, NaOH concentration, temperature, plasma applying time and plasma gases effects. The results of the activity tests indicate that the choice of Cr and the catalyst composition greatly influenced the activity as well as the selectivity for hydrogen generation from the hydrolysis of NaBH4. The Cr0.0125-Ni-W-B catalyst was treated with argon, nitrogen and carbon dioxide plasma at different treatment times. The catalysts were characterized using SEM, BET surface area measurement and XRD.

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