TY - JOUR
T1 - Hydrogen generation from catalytic hydrolysis of sodium borohydride by a novel Co(II)-Cu(II) based complex catalyst
AU - Kilinç, Dilek
AU - Saka, Cafer
AU - Şahin, Ömer
PY - 2012/11/1
Y1 - 2012/11/1
N2 - In the present work, Co(II)-Cu(II) supported salicylaldimine derivatives complex catalysts and their mixtures are tested for hydrogen generation from the hydrolysis reaction of sodium borohydride (NaBH 4). The hydrolysis of NaBH 4 with Co(II)-Cu(II) supported complex catalysts is investigated depending on the Co(II)-Cu(II) ratio, NaBH 4 concentration, NaOH concentration, temperature and catalyst amount. The results suggested that the optimal mixture percentage of Co(II)-Cu(II) catalyst is 40:60. The obtained complex catalysts are characterized by XRD, FT-IR and SEM techniques and evaluated for their activity for the hydrogen generation from the hydrolysis reaction of NaBH 4.
AB - In the present work, Co(II)-Cu(II) supported salicylaldimine derivatives complex catalysts and their mixtures are tested for hydrogen generation from the hydrolysis reaction of sodium borohydride (NaBH 4). The hydrolysis of NaBH 4 with Co(II)-Cu(II) supported complex catalysts is investigated depending on the Co(II)-Cu(II) ratio, NaBH 4 concentration, NaOH concentration, temperature and catalyst amount. The results suggested that the optimal mixture percentage of Co(II)-Cu(II) catalyst is 40:60. The obtained complex catalysts are characterized by XRD, FT-IR and SEM techniques and evaluated for their activity for the hydrogen generation from the hydrolysis reaction of NaBH 4.
KW - Copper-Cobalt complex catalysts
KW - Hydrogen generation
KW - Sodium borohydride hydrolysis
UR - http://www.scopus.com/inward/record.url?scp=84862997765&partnerID=8YFLogxK
U2 - 10.1016/j.jpowsour.2012.06.018
DO - 10.1016/j.jpowsour.2012.06.018
M3 - Article
AN - SCOPUS:84862997765
SN - 0378-7753
VL - 217
SP - 256
EP - 261
JO - Journal of Power Sources
JF - Journal of Power Sources
ER -