High hydrogen production rate from potassium borohydride hydrolysis with an efficient catalyst: CNT@Ru(0)

M. Salih Keskin; Mehmet Salih Ağirtaş; Orhan Baytar; M. Sait İzgi; Ömer Şahin; Sabit Horoz

doi:10.5004/dwt.2022.28166

High hydrogen production rate from potassium borohydride hydrolysis with an efficient catalyst: CNT@Ru(0)

M. Salih Keskin^*, Mehmet Salih Ağirtaş, Orhan Baytar, M. Sait İzgi, Ömer Şahin, Sabit Horoz

^*Corresponding author for this work

Department of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

We describe the production and catalytic activity of a carbon nanotube supported-Ru(0) (CNT@ Ru(0)) catalyst. For the first time, the produced CNT@Ru(0) catalyst is used to achieve the greatest hydrogen production rate from potassium borohydride (KBH₄ ) hydrolysis. The produced CNT@ Ru(0) catalyst shows promise in the creation of hydrogen from the degradation of KBH₄ . The hydrogen generation rate of CNT@Ru(0) is determined to be 86,264.85 mL min^–1 can with a low activation energy of 30.18 kJ mol⁻¹. CNTs are potential support for distributing metal catalysts, according to the current work. Furthermore, structural, morphological, and elemental characteristics of the produced CNT@Ru(0) catalyst are investigated.

Original language	English
Pages (from-to)	189-196
Number of pages	8
Journal	Desalination and Water Treatment
Volume	250
DOIs	https://doi.org/10.5004/dwt.2022.28166
Publication status	Published - Feb 2022

Bibliographical note

Publisher Copyright:
© 2022 Desalination Publications. All rights reserved.

Funding

The authors are grateful to the Research Foundation of yüzüncü yıl University for financial support under project FDK-2017-6256.

Funders	Funder number
Research Foundation of yüzüncü yıl University	FDK-2017-6256

Keywords

Catalyst
Hydrogen
Potassium borohydride
Ruthenium

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.5004/dwt.2022.28166

Cite this

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title = "High hydrogen production rate from potassium borohydride hydrolysis with an efficient catalyst: CNT@Ru(0)",

abstract = "We describe the production and catalytic activity of a carbon nanotube supported-Ru(0) (CNT@ Ru(0)) catalyst. For the first time, the produced CNT@Ru(0) catalyst is used to achieve the greatest hydrogen production rate from potassium borohydride (KBH4 ) hydrolysis. The produced CNT@ Ru(0) catalyst shows promise in the creation of hydrogen from the degradation of KBH4 . The hydrogen generation rate of CNT@Ru(0) is determined to be 86,264.85 mL min–1 can with a low activation energy of 30.18 kJ mol−1. CNTs are potential support for distributing metal catalysts, according to the current work. Furthermore, structural, morphological, and elemental characteristics of the produced CNT@Ru(0) catalyst are investigated.",

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doi = "10.5004/dwt.2022.28166",

language = "English",

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journal = "Desalination and Water Treatment",

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T1 - High hydrogen production rate from potassium borohydride hydrolysis with an efficient catalyst

T2 - CNT@Ru(0)

AU - Keskin, M. Salih

AU - Ağirtaş, Mehmet Salih

AU - Baytar, Orhan

AU - Sait İzgi, M.

AU - Şahin, Ömer

AU - Horoz, Sabit

PY - 2022/2

Y1 - 2022/2

N2 - We describe the production and catalytic activity of a carbon nanotube supported-Ru(0) (CNT@ Ru(0)) catalyst. For the first time, the produced CNT@Ru(0) catalyst is used to achieve the greatest hydrogen production rate from potassium borohydride (KBH4 ) hydrolysis. The produced CNT@ Ru(0) catalyst shows promise in the creation of hydrogen from the degradation of KBH4 . The hydrogen generation rate of CNT@Ru(0) is determined to be 86,264.85 mL min–1 can with a low activation energy of 30.18 kJ mol−1. CNTs are potential support for distributing metal catalysts, according to the current work. Furthermore, structural, morphological, and elemental characteristics of the produced CNT@Ru(0) catalyst are investigated.

AB - We describe the production and catalytic activity of a carbon nanotube supported-Ru(0) (CNT@ Ru(0)) catalyst. For the first time, the produced CNT@Ru(0) catalyst is used to achieve the greatest hydrogen production rate from potassium borohydride (KBH4 ) hydrolysis. The produced CNT@ Ru(0) catalyst shows promise in the creation of hydrogen from the degradation of KBH4 . The hydrogen generation rate of CNT@Ru(0) is determined to be 86,264.85 mL min–1 can with a low activation energy of 30.18 kJ mol−1. CNTs are potential support for distributing metal catalysts, according to the current work. Furthermore, structural, morphological, and elemental characteristics of the produced CNT@Ru(0) catalyst are investigated.

KW - Catalyst

KW - Hydrogen

KW - Potassium borohydride

KW - Ruthenium

UR - https://www.scopus.com/pages/publications/85126759225

U2 - 10.5004/dwt.2022.28166

DO - 10.5004/dwt.2022.28166

M3 - Article

AN - SCOPUS:85126759225

SN - 1944-3994

VL - 250

SP - 189

EP - 196

JO - Desalination and Water Treatment

JF - Desalination and Water Treatment

ER -

High hydrogen production rate from potassium borohydride hydrolysis with an efficient catalyst: CNT@Ru(0)

Abstract

Bibliographical note

Funding

Keywords

UN SDGs

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