Heteroarm H-shaped terpolymers through click reaction

Eda Gungor; Gulay Cote; Tuba Erdogan; Hakan Durmaz; A. Levent Demirel; Gurkan Hizal; Umit Tunca

doi:10.1002/pola.21863

Heteroarm H-shaped terpolymers through click reaction

Eda Gungor, Gulay Cote, Tuba Erdogan, Hakan Durmaz, A. Levent Demirel, Gurkan Hizal, Umit Tunca^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

61 Citations (Scopus)

Abstract

Heteroarm H-shaped terpolymers, (polystyrene)(poly(methyl methacrylate))-poly(tert-butyl acrylate)-(polystyrene)(poly(methyl methacrylate)), (PS)(PMMA)-PtBA-(PMMA)(PS), and, (PS)(PMMA)-poly(ethylene glycol)(PEG)-(PMMA)(PS), through click reaction strategy between PS-PMMA copolymer (as side chains) with an alkyne functional group at the junction point and diazide end-functionalized PtBA or PEG (as a main chain). PS-PMMA with alkyne functional group was prepared by sequential living radical polymerizations such as the nitroxide mediated (NMP) and the metal mediated-living radical polymerization (ATRP) routes. The obtained H-shaped polymers were characterized by using ¹H-NMR, GPC, DSC, and AFM measurements.

Original language	English
Pages (from-to)	1055-1065
Number of pages	11
Journal	Journal of Polymer Science, Part A: Polymer Chemistry
Volume	45
Issue number	6
DOIs	https://doi.org/10.1002/pola.21863
Publication status	Published - 15 Mar 2007

Keywords

Atom transfer radical polymerization
Atomic force microscopy
Click reaction
H-shaped polymers
Living polymerization
Nitroxide mediated radical polymerization
Poly(ethylene glycol)
Poly(methyl methacrylate)
Poly(tert-butyl acrylate)

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10.1002/pola.21863

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title = "Heteroarm H-shaped terpolymers through click reaction",

abstract = "Heteroarm H-shaped terpolymers, (polystyrene)(poly(methyl methacrylate))-poly(tert-butyl acrylate)-(polystyrene)(poly(methyl methacrylate)), (PS)(PMMA)-PtBA-(PMMA)(PS), and, (PS)(PMMA)-poly(ethylene glycol)(PEG)-(PMMA)(PS), through click reaction strategy between PS-PMMA copolymer (as side chains) with an alkyne functional group at the junction point and diazide end-functionalized PtBA or PEG (as a main chain). PS-PMMA with alkyne functional group was prepared by sequential living radical polymerizations such as the nitroxide mediated (NMP) and the metal mediated-living radical polymerization (ATRP) routes. The obtained H-shaped polymers were characterized by using 1H-NMR, GPC, DSC, and AFM measurements.",

keywords = "Atom transfer radical polymerization, Atomic force microscopy, Click reaction, H-shaped polymers, Living polymerization, Nitroxide mediated radical polymerization, Poly(ethylene glycol), Poly(methyl methacrylate), Poly(tert-butyl acrylate)",

author = "Eda Gungor and Gulay Cote and Tuba Erdogan and Hakan Durmaz and Demirel, {A. Levent} and Gurkan Hizal and Umit Tunca",

year = "2007",

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volume = "45",

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AU - Gungor, Eda

AU - Cote, Gulay

AU - Erdogan, Tuba

AU - Durmaz, Hakan

AU - Demirel, A. Levent

AU - Hizal, Gurkan

AU - Tunca, Umit

PY - 2007/3/15

Y1 - 2007/3/15

N2 - Heteroarm H-shaped terpolymers, (polystyrene)(poly(methyl methacrylate))-poly(tert-butyl acrylate)-(polystyrene)(poly(methyl methacrylate)), (PS)(PMMA)-PtBA-(PMMA)(PS), and, (PS)(PMMA)-poly(ethylene glycol)(PEG)-(PMMA)(PS), through click reaction strategy between PS-PMMA copolymer (as side chains) with an alkyne functional group at the junction point and diazide end-functionalized PtBA or PEG (as a main chain). PS-PMMA with alkyne functional group was prepared by sequential living radical polymerizations such as the nitroxide mediated (NMP) and the metal mediated-living radical polymerization (ATRP) routes. The obtained H-shaped polymers were characterized by using 1H-NMR, GPC, DSC, and AFM measurements.

AB - Heteroarm H-shaped terpolymers, (polystyrene)(poly(methyl methacrylate))-poly(tert-butyl acrylate)-(polystyrene)(poly(methyl methacrylate)), (PS)(PMMA)-PtBA-(PMMA)(PS), and, (PS)(PMMA)-poly(ethylene glycol)(PEG)-(PMMA)(PS), through click reaction strategy between PS-PMMA copolymer (as side chains) with an alkyne functional group at the junction point and diazide end-functionalized PtBA or PEG (as a main chain). PS-PMMA with alkyne functional group was prepared by sequential living radical polymerizations such as the nitroxide mediated (NMP) and the metal mediated-living radical polymerization (ATRP) routes. The obtained H-shaped polymers were characterized by using 1H-NMR, GPC, DSC, and AFM measurements.

KW - Atom transfer radical polymerization

KW - Atomic force microscopy

KW - Click reaction

KW - H-shaped polymers

KW - Living polymerization

KW - Nitroxide mediated radical polymerization

KW - Poly(ethylene glycol)

KW - Poly(methyl methacrylate)

KW - Poly(tert-butyl acrylate)

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U2 - 10.1002/pola.21863

DO - 10.1002/pola.21863

M3 - Article

AN - SCOPUS:33947594012

SN - 0887-624X

VL - 45

SP - 1055

EP - 1065

JO - Journal of Polymer Science, Part A: Polymer Chemistry

JF - Journal of Polymer Science, Part A: Polymer Chemistry

IS - 6

ER -

Heteroarm H-shaped terpolymers through click reaction

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Keywords

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