Graphene oxide induced chemiluminescence used for quenchometric determination of dobutamine hydrochloride

Mortaza Iranifam; Paria Razavi Babakalak; Amin Imani-Nabiyyi; Mir Mahdi Abolghasemi; Alireza Khataee

doi:10.1039/c6ay00363j

Graphene oxide induced chemiluminescence used for quenchometric determination of dobutamine hydrochloride

Mortaza Iranifam^*, Paria Razavi Babakalak, Amin Imani-Nabiyyi, Mir Mahdi Abolghasemi, Alireza Khataee

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

In the present study, a simple, rapid, sensitive, and environmentally friendly method was proposed for the determination of dobutamine hydrochloride (Dbn.HCl). The method is based on the inhibition of the chemiluminescence (CL) arising from the reaction of luminol and graphene oxide (GO) in a strongly alkaline medium by Dbn.HCl. GO was synthesized and fully characterized by various spectroscopic methods, including TEM and SEM. The mechanisms of the generation and inhibition of CL were also investigated and discussed. The experimental conditions were optimized and under optimum conditions, the method showed a linear response for Dbn.HCl over the concentration range from 3.0 × 10^-7 to 5.0 × 10^-6 mol L^-1. The correlation coefficient (r²) of the calibration line was 0.9972, and the relative standard deviation (RSD) of the method obtained by nine replicate determinations of 2.0 × 10^-6 mol L^-1 Dbn.HCl was equal to 1.2%. The method was successfully used for the determination of Dbn.HCl in various real samples.

Original language	English
Pages (from-to)	3496-3502
Number of pages	7
Journal	Analytical Methods
Volume	8
Issue number	17
DOIs	https://doi.org/10.1039/c6ay00363j
Publication status	Published - 7 May 2016
Externally published	Yes

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© 2016 The Royal Society of Chemistry.

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title = "Graphene oxide induced chemiluminescence used for quenchometric determination of dobutamine hydrochloride",

abstract = "In the present study, a simple, rapid, sensitive, and environmentally friendly method was proposed for the determination of dobutamine hydrochloride (Dbn.HCl). The method is based on the inhibition of the chemiluminescence (CL) arising from the reaction of luminol and graphene oxide (GO) in a strongly alkaline medium by Dbn.HCl. GO was synthesized and fully characterized by various spectroscopic methods, including TEM and SEM. The mechanisms of the generation and inhibition of CL were also investigated and discussed. The experimental conditions were optimized and under optimum conditions, the method showed a linear response for Dbn.HCl over the concentration range from 3.0 × 10-7 to 5.0 × 10-6 mol L-1. The correlation coefficient (r2) of the calibration line was 0.9972, and the relative standard deviation (RSD) of the method obtained by nine replicate determinations of 2.0 × 10-6 mol L-1 Dbn.HCl was equal to 1.2%. The method was successfully used for the determination of Dbn.HCl in various real samples.",

author = "Mortaza Iranifam and Babakalak, {Paria Razavi} and Amin Imani-Nabiyyi and Abolghasemi, {Mir Mahdi} and Alireza Khataee",

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T1 - Graphene oxide induced chemiluminescence used for quenchometric determination of dobutamine hydrochloride

AU - Iranifam, Mortaza

AU - Babakalak, Paria Razavi

AU - Imani-Nabiyyi, Amin

AU - Abolghasemi, Mir Mahdi

AU - Khataee, Alireza

PY - 2016/5/7

Y1 - 2016/5/7

N2 - In the present study, a simple, rapid, sensitive, and environmentally friendly method was proposed for the determination of dobutamine hydrochloride (Dbn.HCl). The method is based on the inhibition of the chemiluminescence (CL) arising from the reaction of luminol and graphene oxide (GO) in a strongly alkaline medium by Dbn.HCl. GO was synthesized and fully characterized by various spectroscopic methods, including TEM and SEM. The mechanisms of the generation and inhibition of CL were also investigated and discussed. The experimental conditions were optimized and under optimum conditions, the method showed a linear response for Dbn.HCl over the concentration range from 3.0 × 10-7 to 5.0 × 10-6 mol L-1. The correlation coefficient (r2) of the calibration line was 0.9972, and the relative standard deviation (RSD) of the method obtained by nine replicate determinations of 2.0 × 10-6 mol L-1 Dbn.HCl was equal to 1.2%. The method was successfully used for the determination of Dbn.HCl in various real samples.

AB - In the present study, a simple, rapid, sensitive, and environmentally friendly method was proposed for the determination of dobutamine hydrochloride (Dbn.HCl). The method is based on the inhibition of the chemiluminescence (CL) arising from the reaction of luminol and graphene oxide (GO) in a strongly alkaline medium by Dbn.HCl. GO was synthesized and fully characterized by various spectroscopic methods, including TEM and SEM. The mechanisms of the generation and inhibition of CL were also investigated and discussed. The experimental conditions were optimized and under optimum conditions, the method showed a linear response for Dbn.HCl over the concentration range from 3.0 × 10-7 to 5.0 × 10-6 mol L-1. The correlation coefficient (r2) of the calibration line was 0.9972, and the relative standard deviation (RSD) of the method obtained by nine replicate determinations of 2.0 × 10-6 mol L-1 Dbn.HCl was equal to 1.2%. The method was successfully used for the determination of Dbn.HCl in various real samples.

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SN - 1759-9660

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EP - 3502

JO - Analytical Methods

JF - Analytical Methods

IS - 17

ER -

Graphene oxide induced chemiluminescence used for quenchometric determination of dobutamine hydrochloride

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