Fullerene-Attached Polymeric Homogeneous/Heterogeneous Photoactivators for Visible-Light-Induced CuAAC Click Reactions

Omer S. Taskin; Gorkem Yilmaz; Yusuf Yagci

doi:10.1021/acsmacrolett.5b00885

Fullerene-Attached Polymeric Homogeneous/Heterogeneous Photoactivators for Visible-Light-Induced CuAAC Click Reactions

Omer S. Taskin
, Gorkem Yilmaz
, Yusuf Yagci^*

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University
Faculty of Sciences, King Abdulaziz University

Research output: Contribution to journal › Article › peer-review

34 Citations (Scopus)

Abstract

In this work, a visible-light-induced copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC) click reaction via an electron transfer reaction employing fullerene (C₆₀) containing linear polystyrene and network polymer as homogeneous and heterogeneous activators, PS-C₆₀ and Gel-C₆₀, respectively, is described. Various low molar mass organic and polymeric azide and alkyne compounds are used to conduct the click reaction, and almost quantitative yields are attained. Compared to the bare C₆₀, the polymers with C₆₀ units exhibited a much higher promoting effect to catalyze CuAAC reactions.

Original language	English
Pages (from-to)	103-107
Number of pages	5
Journal	ACS Macro Letters
Volume	5
Issue number	1
DOIs	https://doi.org/10.1021/acsmacrolett.5b00885
Publication status	Published - 19 Jan 2016

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© 2015 American Chemical Society.

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abstract = "In this work, a visible-light-induced copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC) click reaction via an electron transfer reaction employing fullerene (C60) containing linear polystyrene and network polymer as homogeneous and heterogeneous activators, PS-C60 and Gel-C60, respectively, is described. Various low molar mass organic and polymeric azide and alkyne compounds are used to conduct the click reaction, and almost quantitative yields are attained. Compared to the bare C60, the polymers with C60 units exhibited a much higher promoting effect to catalyze CuAAC reactions.",

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Fullerene-Attached Polymeric Homogeneous/Heterogeneous Photoactivators for Visible-Light-Induced CuAAC Click Reactions

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