Formation of α-SiAlON ceramics containing scandium

S. Kurama*, H. Mandal

*Corresponding author for this work

Research output: Contribution to journalConference articlepeer-review

2 Citations (Scopus)

Abstract

α-SiAlON is able to accommodate cations into its crystal structure if the cations are sufficiently small in size, thus helping to reduce the volume of the remnant grain boundary phase after processing. Lutetium with an ionic radius of 0.85 Å was the smallest 3+ cation which can be incorporated into α-SiAlON structure and the Sc+3 cation, with an ionic radius of 0.73 Å was accepted too small to form an α-SiAlON. In the present work, the possibility of having the Sc+3 as a dopant cation into α-SiAlON structure has been investigated. XRD and energy dispersive X-ray measurements (EDX) analyses have proven that Sc+3 cations can be accommodated into α-SiAlON structure.

Original languageEnglish
Pages (from-to)1107-1110
Number of pages4
JournalKey Engineering Materials
Volume264-268
Issue numberII
DOIs
Publication statusPublished - 2004
Externally publishedYes
EventProceedings of the 8th Conference and Exhibition of the European Ceramic Society - Istanbul, Turkey
Duration: 29 Jun 20033 Jul 2003

Keywords

  • Phase Relationship
  • Scandium Cation
  • α-SiAlON

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