Fluorescence quenching method for measuring monomer consumption rates during free-radical crosslinking copolymerization

Ö Pekcan; D. Kaya; M. Erdoan

doi:10.1002/app.1288

Fluorescence quenching method for measuring monomer consumption rates during free-radical crosslinking copolymerization

Ö Pekcan^*
, D. Kaya
, M. Erdoan

^*Corresponding author for this work

Department of Physics Engineering

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The steady-state fluorescence (SSF) technique was used to study the polymerization rate in free-radical crosslinking copolymerization (FCC) of methyl methacrylate (MMA) and ethylene glycol dimethacrylate (EGDM). Pyrene (Py) was used as a fluorescent probe for the in situ polymerization experiments. The increase in Py intensity was monitored during FCC. The Stern-Volmer kinetic was employed to determine the MMA consumption rate during gelation process for various EGDM contents and at different temperatures.

Original language	English
Pages (from-to)	1907-1913
Number of pages	7
Journal	Journal of Applied Polymer Science
Volume	80
Issue number	11
DOIs	https://doi.org/10.1002/app.1288
Publication status	Published - 13 Jun 2001

Keywords

Fluorescence
Gelation
Monomer consumption
Polymerization rates

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10.1002/app.1288

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abstract = "The steady-state fluorescence (SSF) technique was used to study the polymerization rate in free-radical crosslinking copolymerization (FCC) of methyl methacrylate (MMA) and ethylene glycol dimethacrylate (EGDM). Pyrene (Py) was used as a fluorescent probe for the in situ polymerization experiments. The increase in Py intensity was monitored during FCC. The Stern-Volmer kinetic was employed to determine the MMA consumption rate during gelation process for various EGDM contents and at different temperatures.",

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AU - Pekcan, Ö

AU - Kaya, D.

AU - Erdoan, M.

PY - 2001/6/13

Y1 - 2001/6/13

N2 - The steady-state fluorescence (SSF) technique was used to study the polymerization rate in free-radical crosslinking copolymerization (FCC) of methyl methacrylate (MMA) and ethylene glycol dimethacrylate (EGDM). Pyrene (Py) was used as a fluorescent probe for the in situ polymerization experiments. The increase in Py intensity was monitored during FCC. The Stern-Volmer kinetic was employed to determine the MMA consumption rate during gelation process for various EGDM contents and at different temperatures.

AB - The steady-state fluorescence (SSF) technique was used to study the polymerization rate in free-radical crosslinking copolymerization (FCC) of methyl methacrylate (MMA) and ethylene glycol dimethacrylate (EGDM). Pyrene (Py) was used as a fluorescent probe for the in situ polymerization experiments. The increase in Py intensity was monitored during FCC. The Stern-Volmer kinetic was employed to determine the MMA consumption rate during gelation process for various EGDM contents and at different temperatures.

KW - Fluorescence

KW - Gelation

KW - Monomer consumption

KW - Polymerization rates

UR - https://www.scopus.com/pages/publications/0035854130

U2 - 10.1002/app.1288

DO - 10.1002/app.1288

M3 - Article

AN - SCOPUS:0035854130

SN - 0021-8995

VL - 80

SP - 1907

EP - 1913

JO - Journal of Applied Polymer Science

JF - Journal of Applied Polymer Science

IS - 11

ER -

Fluorescence quenching method for measuring monomer consumption rates during free-radical crosslinking copolymerization

Abstract

Keywords

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