Abstract
The steady-state fluorescence (SSF) technique was used to study the polymerization rate in free-radical crosslinking copolymerization (FCC) of methyl methacrylate (MMA) and ethylene glycol dimethacrylate (EGDM). Pyrene (Py) was used as a fluorescent probe for the in situ polymerization experiments. The increase in Py intensity was monitored during FCC. The Stern-Volmer kinetic was employed to determine the MMA consumption rate during gelation process for various EGDM contents and at different temperatures.
Original language | English |
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Pages (from-to) | 1907-1913 |
Number of pages | 7 |
Journal | Journal of Applied Polymer Science |
Volume | 80 |
Issue number | 11 |
DOIs | |
Publication status | Published - 13 Jun 2001 |
Keywords
- Fluorescence
- Gelation
- Monomer consumption
- Polymerization rates