Fabrication of silane-modified magnetic nano sorbent for enhanced ultrasonic wave driven removal of methylene blue from aqueous media: Isotherms, kinetics, and thermodynamic mechanistic studies

Abdullah; Esra Alveroğlu Durucu; Aamna Balouch; Ali Muhammad Mahar

doi:10.3906/KIM-2007-66

Fabrication of silane-modified magnetic nano sorbent for enhanced ultrasonic wave driven removal of methylene blue from aqueous media: Isotherms, kinetics, and thermodynamic mechanistic studies

Abdullah, Esra Alveroğlu Durucu, Aamna Balouch^*, Ali Muhammad Mahar

^*Corresponding author for this work

Department of Physics Engineering

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

In this study, we report a simple and economic one-pot synthesis of magnetite (Fe₃O₄) nanostructure and its modification with tetraethyl orthosilicate by coprecipitation method. The synthesized (Fe₃O₄@SiO₂) nano sorbent was applied for enhanced adsorptive removal of methylene blue by ultrasonic wave driven batch experiments. After successful synthesis, the nanostructure was characterized for their physical structure by FT-IR, VSM, TEM, and XRD. For the maximum adsorptive performance of nano sorbent, various parameters were optimized, such as dose, pH, time, concentration, and temperature. The adsorption mechanism was best fitted by Langmuir isotherm with a maximum capacity of 148.69 mg/g, while kinetics best fitted by pseudo-second-order kinetic. The synthesized nano sorbent was successfully applied for enhanced adsorptive removal of toxic methylene blue from aqueous media. The proposed method is promising and effective in terms of simplicity, cost operation, green energy consumption, reproducible, excellent reusability, and magnetically separability with fast kinetic.

Original language	English
Pages (from-to)	181-191
Number of pages	11
Journal	Turkish Journal of Chemistry
Volume	45
Issue number	1
DOIs	https://doi.org/10.3906/KIM-2007-66
Publication status	Published - 2021

Bibliographical note

Publisher Copyright:
© This work is licensed under a Creative Commons Attribution 4.0 International License.

Funding

This work was fully acknowledged by the scholarship from “Scientific and Technological Research Council of Turkey (BIDEB-2221) Research Fellowship Program for International Citizens.”

Funders	Funder number
Türkiye Bilimsel ve Teknolojik Araştirma Kurumu	BIDEB-2221

Keywords

FeO@SiO
Methylene blue
Tetraethyl orthosilicate
Ultrasonic wave

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.3906/KIM-2007-66

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title = "Fabrication of silane-modified magnetic nano sorbent for enhanced ultrasonic wave driven removal of methylene blue from aqueous media: Isotherms, kinetics, and thermodynamic mechanistic studies",

abstract = "In this study, we report a simple and economic one-pot synthesis of magnetite (Fe3O4) nanostructure and its modification with tetraethyl orthosilicate by coprecipitation method. The synthesized (Fe3O4@SiO2) nano sorbent was applied for enhanced adsorptive removal of methylene blue by ultrasonic wave driven batch experiments. After successful synthesis, the nanostructure was characterized for their physical structure by FT-IR, VSM, TEM, and XRD. For the maximum adsorptive performance of nano sorbent, various parameters were optimized, such as dose, pH, time, concentration, and temperature. The adsorption mechanism was best fitted by Langmuir isotherm with a maximum capacity of 148.69 mg/g, while kinetics best fitted by pseudo-second-order kinetic. The synthesized nano sorbent was successfully applied for enhanced adsorptive removal of toxic methylene blue from aqueous media. The proposed method is promising and effective in terms of simplicity, cost operation, green energy consumption, reproducible, excellent reusability, and magnetically separability with fast kinetic.",

keywords = "FeO@SiO, Methylene blue, Tetraethyl orthosilicate, Ultrasonic wave",

author = "Abdullah and {Alveroğlu Durucu}, Esra and Aamna Balouch and Mahar, {Ali Muhammad}",

note = "Publisher Copyright: {\textcopyright} This work is licensed under a Creative Commons Attribution 4.0 International License.",

year = "2021",

doi = "10.3906/KIM-2007-66",

language = "English",

volume = "45",

pages = "181--191",

journal = "Turkish Journal of Chemistry",

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Fabrication of silane-modified magnetic nano sorbent for enhanced ultrasonic wave driven removal of methylene blue from aqueous media: Isotherms, kinetics, and thermodynamic mechanistic studies. / Abdullah, ; Alveroğlu Durucu, Esra; Balouch, Aamna et al.
In: Turkish Journal of Chemistry, Vol. 45, No. 1, 2021, p. 181-191.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Fabrication of silane-modified magnetic nano sorbent for enhanced ultrasonic wave driven removal of methylene blue from aqueous media

T2 - Isotherms, kinetics, and thermodynamic mechanistic studies

AU - Abdullah,

AU - Alveroğlu Durucu, Esra

AU - Balouch, Aamna

AU - Mahar, Ali Muhammad

PY - 2021

Y1 - 2021

N2 - In this study, we report a simple and economic one-pot synthesis of magnetite (Fe3O4) nanostructure and its modification with tetraethyl orthosilicate by coprecipitation method. The synthesized (Fe3O4@SiO2) nano sorbent was applied for enhanced adsorptive removal of methylene blue by ultrasonic wave driven batch experiments. After successful synthesis, the nanostructure was characterized for their physical structure by FT-IR, VSM, TEM, and XRD. For the maximum adsorptive performance of nano sorbent, various parameters were optimized, such as dose, pH, time, concentration, and temperature. The adsorption mechanism was best fitted by Langmuir isotherm with a maximum capacity of 148.69 mg/g, while kinetics best fitted by pseudo-second-order kinetic. The synthesized nano sorbent was successfully applied for enhanced adsorptive removal of toxic methylene blue from aqueous media. The proposed method is promising and effective in terms of simplicity, cost operation, green energy consumption, reproducible, excellent reusability, and magnetically separability with fast kinetic.

AB - In this study, we report a simple and economic one-pot synthesis of magnetite (Fe3O4) nanostructure and its modification with tetraethyl orthosilicate by coprecipitation method. The synthesized (Fe3O4@SiO2) nano sorbent was applied for enhanced adsorptive removal of methylene blue by ultrasonic wave driven batch experiments. After successful synthesis, the nanostructure was characterized for their physical structure by FT-IR, VSM, TEM, and XRD. For the maximum adsorptive performance of nano sorbent, various parameters were optimized, such as dose, pH, time, concentration, and temperature. The adsorption mechanism was best fitted by Langmuir isotherm with a maximum capacity of 148.69 mg/g, while kinetics best fitted by pseudo-second-order kinetic. The synthesized nano sorbent was successfully applied for enhanced adsorptive removal of toxic methylene blue from aqueous media. The proposed method is promising and effective in terms of simplicity, cost operation, green energy consumption, reproducible, excellent reusability, and magnetically separability with fast kinetic.

KW - FeO@SiO

KW - Methylene blue

KW - Tetraethyl orthosilicate

KW - Ultrasonic wave

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DO - 10.3906/KIM-2007-66

M3 - Article

AN - SCOPUS:85102300830

SN - 1300-0527

VL - 45

SP - 181

EP - 191

JO - Turkish Journal of Chemistry

JF - Turkish Journal of Chemistry

IS - 1

ER -

Fabrication of silane-modified magnetic nano sorbent for enhanced ultrasonic wave driven removal of methylene blue from aqueous media: Isotherms, kinetics, and thermodynamic mechanistic studies

Abstract

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Keywords

UN SDGs

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