Expanded polylactide bead foaming - A new technology

M. Nofar, A. Ameli, C. B. Park

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

3 Citations (Scopus)

Abstract

Bead foaming technology with double crystal melting peak structure has been recognized as a promising method to produce low-density foams with complex geometries. During the molding stage of the bead foams, the double peak structure generates a strong bead-to-bead sintering and maintains the overall foam structure. During recent years, polylactide (PLA) bead foaming has been of the great interest of researchers due to its origin from renewable resources and biodegradability. However, due to the PLA's low melt strength and slow crystallization kinetics, the attempts have been limited to the manufacturing methods used for expanded polystyrene. In this study, for the first time, we developed microcellular PLA bead foams with double crystal melting peak structure. Microcellular PLA bead foams were produced with expansion ratios and average cell sizes ranging from 3 to 30-times and 350 nm to 15 μm, respectively. The generated high melting temperature crystals during the saturation significantly affected the expansion ratio and cell density of the PLA bead foams by enhancing the PLA's poor melt strength and promoting heterogeneous cell nucleation around the crystals.

Original languageEnglish
Title of host publicationProceedings of PPS-30
Subtitle of host publicationThe 30th International Conference of the Polymer Processing Society - Conference Papers
EditorsSadhan C. Jana
PublisherAmerican Institute of Physics Inc.
ISBN (Electronic)9780735413092
DOIs
Publication statusPublished - 22 May 2015
Externally publishedYes
Event30th International Conference of the Polymer Processing Society, PPS 2014 - Cleveland, United States
Duration: 6 Jun 201412 Jun 2014

Publication series

NameAIP Conference Proceedings
Volume1664
ISSN (Print)0094-243X
ISSN (Electronic)1551-7616

Conference

Conference30th International Conference of the Polymer Processing Society, PPS 2014
Country/TerritoryUnited States
CityCleveland
Period6/06/1412/06/14

Bibliographical note

Publisher Copyright:
© 2015 AIP Publishing LLC.

Keywords

  • Bead Foaming
  • Crystallization
  • Microcellular
  • Nanocellular
  • Polylactide

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