EPR spectra of Cu2+ doped [Zn(sac)2(dmen)] and [Zn(sac)2(paen)] single crystals

R. Biyik; R. Tapramaz; O. Z. Yeşilel

doi:10.1016/j.saa.2006.12.008

EPR spectra of Cu²⁺ doped [Zn(sac)₂(dmen)] and [Zn(sac)₂(paen)] single crystals

R. Biyik^*, R. Tapramaz, O. Z. Yeşilel

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

Cu²⁺ doped single crystals of [Zn(sac)₂(dmen)] (sac: saccharinate, dmen: N,N′-dimethylethylendiamine) and [Zn(sac)₂(paen)], (paen: N,N′-bis(3-propylamine)ethylendiamine) complexes have been investigated by electron paramagnetic resonance (EPR) technique. Detailed investigations of the EPR spectra indicate that Cu²⁺ ion substitute with Zn²⁺ ion and forms tetrahedral complex in [Zn(sac)₂(dmen)] and octahedral complex in [Zn(sac)₂(paen)] hosts. Principal values of the g and hyperfine tensors are determined and the ground state wave functions of Cu²⁺ ions are obtained using EPR parameters.

Original language	English
Pages (from-to)	394-398
Number of pages	5
Journal	Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
Volume	68
Issue number	2
DOIs	https://doi.org/10.1016/j.saa.2006.12.008
Publication status	Published - Oct 2007
Externally published	Yes

Keywords

Copper
Doping
EPR
Saccharin
Zinc

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10.1016/j.saa.2006.12.008

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title = "EPR spectra of Cu2+ doped [Zn(sac)2(dmen)] and [Zn(sac)2(paen)] single crystals",

abstract = "Cu2+ doped single crystals of [Zn(sac)2(dmen)] (sac: saccharinate, dmen: N,N′-dimethylethylendiamine) and [Zn(sac)2(paen)], (paen: N,N′-bis(3-propylamine)ethylendiamine) complexes have been investigated by electron paramagnetic resonance (EPR) technique. Detailed investigations of the EPR spectra indicate that Cu2+ ion substitute with Zn2+ ion and forms tetrahedral complex in [Zn(sac)2(dmen)] and octahedral complex in [Zn(sac)2(paen)] hosts. Principal values of the g and hyperfine tensors are determined and the ground state wave functions of Cu2+ ions are obtained using EPR parameters.",

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author = "R. Biyik and R. Tapramaz and Ye{\c s}ilel, {O. Z.}",

year = "2007",

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T1 - EPR spectra of Cu2+ doped [Zn(sac)2(dmen)] and [Zn(sac)2(paen)] single crystals

AU - Biyik, R.

AU - Tapramaz, R.

AU - Yeşilel, O. Z.

PY - 2007/10

Y1 - 2007/10

N2 - Cu2+ doped single crystals of [Zn(sac)2(dmen)] (sac: saccharinate, dmen: N,N′-dimethylethylendiamine) and [Zn(sac)2(paen)], (paen: N,N′-bis(3-propylamine)ethylendiamine) complexes have been investigated by electron paramagnetic resonance (EPR) technique. Detailed investigations of the EPR spectra indicate that Cu2+ ion substitute with Zn2+ ion and forms tetrahedral complex in [Zn(sac)2(dmen)] and octahedral complex in [Zn(sac)2(paen)] hosts. Principal values of the g and hyperfine tensors are determined and the ground state wave functions of Cu2+ ions are obtained using EPR parameters.

AB - Cu2+ doped single crystals of [Zn(sac)2(dmen)] (sac: saccharinate, dmen: N,N′-dimethylethylendiamine) and [Zn(sac)2(paen)], (paen: N,N′-bis(3-propylamine)ethylendiamine) complexes have been investigated by electron paramagnetic resonance (EPR) technique. Detailed investigations of the EPR spectra indicate that Cu2+ ion substitute with Zn2+ ion and forms tetrahedral complex in [Zn(sac)2(dmen)] and octahedral complex in [Zn(sac)2(paen)] hosts. Principal values of the g and hyperfine tensors are determined and the ground state wave functions of Cu2+ ions are obtained using EPR parameters.

KW - Copper

KW - Doping

KW - EPR

KW - Saccharin

KW - Zinc

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DO - 10.1016/j.saa.2006.12.008

M3 - Article

C2 - 17292662

AN - SCOPUS:34548273562

SN - 1386-1425

VL - 68

SP - 394

EP - 398

JO - Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy

JF - Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy

IS - 2

ER -

EPR spectra of Cu²⁺ doped [Zn(sac)₂(dmen)] and [Zn(sac)₂(paen)] single crystals

Abstract

Keywords

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