Enzymatic synthesis and characterization of biodegradable poly(ω-pentadecalactone-co-ε-caprolactone) copolymers

Cansu Ulker*, Yuksel Guvenilir

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

14 Citations (Scopus)

Abstract

As an alternative biodegradable aliphatic polyester, poly(w-pentadecalactone-co-ε-caprolactone) copolymer was synthesized via enzymatic ring-opening polymerization. A new biocatalyst, Candida antarctica lipase B, immobilized onto rice husk ash was used for catalysis. Reactions were carried out at various temperatures and periods for varied copolymer compositions in order to obtain the highest molecular weight copolymer. The best reaction parameters were found to be 80 °C and 6 hours and molecular weights increased proportionally with the amount of w-pentadecalactone (w-PDL). The molecular structure of copolymer with 75% weight ratio of w-PDL (Mn = 19720 g/mol) was characterized by proton and carbon nuclear magnetic resonance spectroscopies (1H-NMR and13C-NMR). Thermal properties of the same copolymer and homopolymers were investigated by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). Improved thermal features were shown by addition of w-PDL to the structure and compared with poly(ε-caprolactone) (PCL). Consequently, poly(w-pentadecalactone-co-ε-caprolactone) copolymers were found to be good alternatives to widely used polyester, PCL, with their rapid polymerization tendency, higher molecular weights, and improved thermal features.

Original languageEnglish
Pages (from-to)591-598
Number of pages8
JournalJournal of Renewable Materials
Volume6
Issue number6
DOIs
Publication statusPublished - Oct 2018

Bibliographical note

Publisher Copyright:
© 2018 Tech Science Press.

Keywords

  • Candida antarctica lipase B
  • Copolymerization
  • Enzymatic ring-opening polymerization
  • Immobilized lipase
  • Lactones
  • Rice husk ash
  • ε-caprolactone
  • ω-pentadecalactone

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