Enhancement of the Surface and Mechanical Properties of Polyurethane Coating Through Changing the Additive Ratio of Silane

İrem Elmas Kant; Simge Tarkuç; Nesrin Köken; Süleyman Alper Yeşilçubuk; Nilgün Kızılcan

doi:10.1002/admi.202300944

Enhancement of the Surface and Mechanical Properties of Polyurethane Coating Through Changing the Additive Ratio of Silane

İrem Elmas Kant, Simge Tarkuç, Nesrin Köken, Süleyman Alper Yeşilçubuk, Nilgün Kızılcan^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Continuous development in the formulation and processing techniques of polyurethane (PU) coatings improves an aesthetic appearance as well as protection against environmental factors. In this study, the formulation of PU coating with polyethylene glycol 600 (PEG600), isophorone diisocyanate (IPDI), and trimethoxysilylpropylcarbamoyloxyhexane (TMSCH) silane-based additive is optimized to obtain high scratch-resistant coating. An addition of 43.1 wt.% TMSCH in PU formulation resulted in a significant improvement in the scratch resistance and wettability properties compared with pure PU film. The homogenously prepared micron-thick coatings are characterized using scanning electron microscopy analysis and Fourier transform infrared spectroscopy. The results confirm the presence of silane additives in the PU coating matrix. The mechanical properties improved due to the increased crosslinking networks via the formation of urethane bonds by increasing the TMSCH in PU formulation. Prepared PU coating showed combined features of transparency, hydrophobicity, scratch resistance, and mechanical strength that make it a promising candidate for household appliances.

Original language	English
Article number	2300944
Journal	Advanced Materials Interfaces
Volume	11
Issue number	11
DOIs	https://doi.org/10.1002/admi.202300944
Publication status	Published - 15 Apr 2024

Bibliographical note

Publisher Copyright:
© 2024 The Authors. Advanced Materials Interfaces published by Wiley-VCH GmbH.

Funding

The authors would like to thank the Scientific and Technical Research Council of Turkey (TUBITAK) 2244 Industrial Ph.D. Program ‐Istanbul Technical University‐Arcelik Project No: 118C104. The authors acknowledge funding from the Research Fund of the Istanbul Technical University, Turkey (ITU BAP; Project No.: TDK‐2022‐43539). The authors would like to acknowledge the financial support from Tubitak 1515 – Frontier R&D Laboratory Support Programme.

Funders	Funder number
Istanbul Technical University, Turkey
Bilimsel Araştırma Projeleri Birimi, İstanbul Teknik Üniversitesi	TDK‐2022‐43539

Keywords

adhesion
coating
hydrophobic
polyurethane
scratch
silane

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10.1002/admi.202300944

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abstract = "Continuous development in the formulation and processing techniques of polyurethane (PU) coatings improves an aesthetic appearance as well as protection against environmental factors. In this study, the formulation of PU coating with polyethylene glycol 600 (PEG600), isophorone diisocyanate (IPDI), and trimethoxysilylpropylcarbamoyloxyhexane (TMSCH) silane-based additive is optimized to obtain high scratch-resistant coating. An addition of 43.1 wt.% TMSCH in PU formulation resulted in a significant improvement in the scratch resistance and wettability properties compared with pure PU film. The homogenously prepared micron-thick coatings are characterized using scanning electron microscopy analysis and Fourier transform infrared spectroscopy. The results confirm the presence of silane additives in the PU coating matrix. The mechanical properties improved due to the increased crosslinking networks via the formation of urethane bonds by increasing the TMSCH in PU formulation. Prepared PU coating showed combined features of transparency, hydrophobicity, scratch resistance, and mechanical strength that make it a promising candidate for household appliances.",

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AU - Köken, Nesrin

AU - Yeşilçubuk, Süleyman Alper

AU - Kızılcan, Nilgün

PY - 2024/4/15

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Enhancement of the Surface and Mechanical Properties of Polyurethane Coating Through Changing the Additive Ratio of Silane

Abstract

Bibliographical note

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Keywords

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