Electrochemical polymerization of pyrrole in acrylamide solution

A. Sezai Saraç; Gürsel Sönmez; Belkis Ustamehmetoglu

doi:10.1016/S0379-6779(98)00188-X

Electrochemical polymerization of pyrrole in acrylamide solution

A. Sezai Saraç^*, Gürsel Sönmez, Belkis Ustamehmetoglu

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

Electrochemical polymerization of pyrrole (Py) in an excess of acrylamide (AAm) was accomplished by using an acetonitrile-tetraethyl ammonium perchlorate (TEAPC) solution containing both monomers. Characterization of soluble and insoluble products was carried out via FT-IR spectrum, cyclic voltammogram (CV), UV-visible spectrum, scanning electron microscope (SEM), differential scanning calorimetry (DSC) and elemental analysis. The role of monomer concentrations on the formation of resulting polymer was investigated. Since the polymerization rate of Py is faster than that of AAm, the appropriate ratio of concentrations of monomers have chosen to have chance to interact AAm with Py oligomers which was formed immediately on the electrode surface. Inclusion of AAm to polymer and the mole ratio of resulting product was reported.

Original language	English
Pages (from-to)	177-182
Number of pages	6
Journal	Synthetic Metals
Volume	98
Issue number	3
DOIs	https://doi.org/10.1016/S0379-6779(98)00188-X
Publication status	Published - 1 Jan 1999

Keywords

Acrylamide
Copolymer
Electrochemical synthesis
Pyrrole

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10.1016/S0379-6779(98)00188-X

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title = "Electrochemical polymerization of pyrrole in acrylamide solution",

abstract = "Electrochemical polymerization of pyrrole (Py) in an excess of acrylamide (AAm) was accomplished by using an acetonitrile-tetraethyl ammonium perchlorate (TEAPC) solution containing both monomers. Characterization of soluble and insoluble products was carried out via FT-IR spectrum, cyclic voltammogram (CV), UV-visible spectrum, scanning electron microscope (SEM), differential scanning calorimetry (DSC) and elemental analysis. The role of monomer concentrations on the formation of resulting polymer was investigated. Since the polymerization rate of Py is faster than that of AAm, the appropriate ratio of concentrations of monomers have chosen to have chance to interact AAm with Py oligomers which was formed immediately on the electrode surface. Inclusion of AAm to polymer and the mole ratio of resulting product was reported.",

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T1 - Electrochemical polymerization of pyrrole in acrylamide solution

AU - Saraç, A. Sezai

AU - Sönmez, Gürsel

AU - Ustamehmetoglu, Belkis

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Y1 - 1999/1/1

N2 - Electrochemical polymerization of pyrrole (Py) in an excess of acrylamide (AAm) was accomplished by using an acetonitrile-tetraethyl ammonium perchlorate (TEAPC) solution containing both monomers. Characterization of soluble and insoluble products was carried out via FT-IR spectrum, cyclic voltammogram (CV), UV-visible spectrum, scanning electron microscope (SEM), differential scanning calorimetry (DSC) and elemental analysis. The role of monomer concentrations on the formation of resulting polymer was investigated. Since the polymerization rate of Py is faster than that of AAm, the appropriate ratio of concentrations of monomers have chosen to have chance to interact AAm with Py oligomers which was formed immediately on the electrode surface. Inclusion of AAm to polymer and the mole ratio of resulting product was reported.

AB - Electrochemical polymerization of pyrrole (Py) in an excess of acrylamide (AAm) was accomplished by using an acetonitrile-tetraethyl ammonium perchlorate (TEAPC) solution containing both monomers. Characterization of soluble and insoluble products was carried out via FT-IR spectrum, cyclic voltammogram (CV), UV-visible spectrum, scanning electron microscope (SEM), differential scanning calorimetry (DSC) and elemental analysis. The role of monomer concentrations on the formation of resulting polymer was investigated. Since the polymerization rate of Py is faster than that of AAm, the appropriate ratio of concentrations of monomers have chosen to have chance to interact AAm with Py oligomers which was formed immediately on the electrode surface. Inclusion of AAm to polymer and the mole ratio of resulting product was reported.

KW - Acrylamide

KW - Copolymer

KW - Electrochemical synthesis

KW - Pyrrole

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VL - 98

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JO - Synthetic Metals

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Electrochemical polymerization of pyrrole in acrylamide solution

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