Electrochemical copolymerization of carbazole, ethylcarbazole and N-vinylcarbazole with methyl ethyl ketone-formaldehyde resin

Belkis Ustamehmetoǧlu; Nilgün Kizilcan; A. Sezai Saraç; Ahmet Akar

doi:10.1080/00914030390207246

Electrochemical copolymerization of carbazole, ethylcarbazole and N-vinylcarbazole with methyl ethyl ketone-formaldehyde resin

Belkis Ustamehmetoǧlu^*, Nilgün Kizilcan, A. Sezai Saraç, Ahmet Akar

^*Corresponding author for this work

Department of Chemistry

Istanbul Technical University

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Electrochemical polymerization of carbazole (Cz), N-Vinylcarbazole (NVCz), and Ethylcarbazole (ECz) in the presence of methyl ethyl ketone formaldehyde resin (MEKF-R) was accomplished by using acetonitrile-NaClO₄ solution. The effects of monomer and resin concentration were investigated on the conductivity of the resulting products. Characterization of insoluble free standing films was carried out via FTIR spectrum, cyclic voltammogram, UV visible spectrum, four point probe conductivity measurements, and elemental analyses. The conductivities of the copolymers were in the range of 10 ^-6-10^-4 S/cm. All copolymers obtained electrochemically were insoluble in solvents.

Original language	English
Pages (from-to)	161-172
Number of pages	12
Journal	International Journal of Polymeric Materials and Polymeric Biomaterials
Volume	54
Issue number	3
DOIs	https://doi.org/10.1080/00914030390207246
Publication status	Published - Mar 2005

Keywords

Carbazole
Conductive polymers
Electrochemical polymerization
Ethylcarbazole
Methyl ethyl ketone formaldehyde resine
N-Vinylcarbazole

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1080/00914030390207246

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@article{3f43cb1052774e80adbc4b9207836a42,

title = "Electrochemical copolymerization of carbazole, ethylcarbazole and N-vinylcarbazole with methyl ethyl ketone-formaldehyde resin",

abstract = "Electrochemical polymerization of carbazole (Cz), N-Vinylcarbazole (NVCz), and Ethylcarbazole (ECz) in the presence of methyl ethyl ketone formaldehyde resin (MEKF-R) was accomplished by using acetonitrile-NaClO4 solution. The effects of monomer and resin concentration were investigated on the conductivity of the resulting products. Characterization of insoluble free standing films was carried out via FTIR spectrum, cyclic voltammogram, UV visible spectrum, four point probe conductivity measurements, and elemental analyses. The conductivities of the copolymers were in the range of 10 -6-10-4 S/cm. All copolymers obtained electrochemically were insoluble in solvents.",

keywords = "Carbazole, Conductive polymers, Electrochemical polymerization, Ethylcarbazole, Methyl ethyl ketone formaldehyde resine, N-Vinylcarbazole",

author = "Belkis Ustamehmetoǧlu and Nilg{\"u}n Kizilcan and Sara{\c c}, {A. Sezai} and Ahmet Akar",

year = "2005",

month = mar,

doi = "10.1080/00914030390207246",

language = "English",

volume = "54",

pages = "161--172",

journal = "International Journal of Polymeric Materials and Polymeric Biomaterials",

issn = "0091-4037",

publisher = "Taylor and Francis Ltd.",

number = "3",

}

Electrochemical copolymerization of carbazole, ethylcarbazole and N-vinylcarbazole with methyl ethyl ketone-formaldehyde resin. / Ustamehmetoǧlu, Belkis ; Kizilcan, Nilgün; Saraç, A. Sezai et al.
In: International Journal of Polymeric Materials and Polymeric Biomaterials, Vol. 54, No. 3, 03.2005, p. 161-172.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Electrochemical copolymerization of carbazole, ethylcarbazole and N-vinylcarbazole with methyl ethyl ketone-formaldehyde resin

AU - Ustamehmetoǧlu, Belkis

AU - Kizilcan, Nilgün

AU - Saraç, A. Sezai

AU - Akar, Ahmet

PY - 2005/3

Y1 - 2005/3

N2 - Electrochemical polymerization of carbazole (Cz), N-Vinylcarbazole (NVCz), and Ethylcarbazole (ECz) in the presence of methyl ethyl ketone formaldehyde resin (MEKF-R) was accomplished by using acetonitrile-NaClO4 solution. The effects of monomer and resin concentration were investigated on the conductivity of the resulting products. Characterization of insoluble free standing films was carried out via FTIR spectrum, cyclic voltammogram, UV visible spectrum, four point probe conductivity measurements, and elemental analyses. The conductivities of the copolymers were in the range of 10 -6-10-4 S/cm. All copolymers obtained electrochemically were insoluble in solvents.

AB - Electrochemical polymerization of carbazole (Cz), N-Vinylcarbazole (NVCz), and Ethylcarbazole (ECz) in the presence of methyl ethyl ketone formaldehyde resin (MEKF-R) was accomplished by using acetonitrile-NaClO4 solution. The effects of monomer and resin concentration were investigated on the conductivity of the resulting products. Characterization of insoluble free standing films was carried out via FTIR spectrum, cyclic voltammogram, UV visible spectrum, four point probe conductivity measurements, and elemental analyses. The conductivities of the copolymers were in the range of 10 -6-10-4 S/cm. All copolymers obtained electrochemically were insoluble in solvents.

KW - Carbazole

KW - Conductive polymers

KW - Electrochemical polymerization

KW - Ethylcarbazole

KW - Methyl ethyl ketone formaldehyde resine

KW - N-Vinylcarbazole

UR - http://www.scopus.com/inward/record.url?scp=19644387689&partnerID=8YFLogxK

U2 - 10.1080/00914030390207246

DO - 10.1080/00914030390207246

M3 - Article

AN - SCOPUS:19644387689

SN - 0091-4037

VL - 54

SP - 161

EP - 172

JO - International Journal of Polymeric Materials and Polymeric Biomaterials

JF - International Journal of Polymeric Materials and Polymeric Biomaterials

IS - 3

ER -

Electrochemical copolymerization of carbazole, ethylcarbazole and N-vinylcarbazole with methyl ethyl ketone-formaldehyde resin

Abstract

Keywords

UN SDGs

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