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Electro-oxidation of pyrite in sodium chloride solutions

  • Fatma Arslan*
  • , Paul F. Duby
  • *Corresponding author for this work
  • Columbia University

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

The mechanism of the electro-oxidation of pyrite in NaCl solutions was investigated. Laboratory work was carried out on the production of hypochlorite and the oxidation of pyrite in an electrochemical cell with a 10% sodium chloride electrolyte at 35-40°C. The production rate of hypochlorite was higher when the pH was not controlled than when it was maintained at the initial value of about 6.5. Pyrite was oxidized by the electrochemically generated hypochlorite, with an overall current efficiency of about 97%. The oxidation rate was directly related to the current and it was not affected by the pulp density.

Original languageEnglish
Pages (from-to)157-169
Number of pages13
JournalHydrometallurgy
Volume46
Issue number1-2
DOIs
Publication statusPublished - Aug 1997

Funding

F. Arslan is grateful to the Turkish Governmenfto r financial support. This research has been partially supported by the Departmento f the Interior's Mineral Institutes Program,a dministerebdy the Bureau of Mines under allotmengt rantn umberG 1184136.

FundersFunder number
Bureau of Mines1184136
Turkish Governmenfto

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