Electrical properties of tetraazamacrocycle-substituted phthalocyanines

Z. Ziya Öztürk; Ahmet Altindal; Ayşegül Gürek; Özer Bekaroǧlu

doi:10.1016/0379-6779(92)90028-H

Electrical properties of tetraazamacrocycle-substituted phthalocyanines

Z. Ziya Öztürk, Ahmet Altindal, Ayşegül Gürek, Özer Bekaroǧlu^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

D.c. and a.c. conductivities of a copper phthalocyanine substituted with four 15-membered tetraazamacrocycles (1) and its pentanuclear complexes are measured as Au/MPc/Au sandwiches in vacuum and in air. Chemical doping with NOBF₄ increases the d.c. conductivity of the order 10². Complexation of the perchlorate salts of Ni^II, Co^II and Cu^II with the macrocycles leads to an increase in the d.c. conductivity of about 10²-10³, but the effects of chloride salts are not so distinct. A.c. conductivities of the phthalocyanines depend on frequency with the empirical formula σ(ω) = A(T)ω^n(T), where n is found to be between 0.37 and 1.20.

Original language	English
Pages (from-to)	291-297
Number of pages	7
Journal	Synthetic Metals
Volume	52
Issue number	3
DOIs	https://doi.org/10.1016/0379-6779(92)90028-H
Publication status	Published - 15 Oct 1992
Externally published	Yes

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title = "Electrical properties of tetraazamacrocycle-substituted phthalocyanines",

abstract = "D.c. and a.c. conductivities of a copper phthalocyanine substituted with four 15-membered tetraazamacrocycles (1) and its pentanuclear complexes are measured as Au/MPc/Au sandwiches in vacuum and in air. Chemical doping with NOBF4 increases the d.c. conductivity of the order 102. Complexation of the perchlorate salts of NiII, CoII and CuII with the macrocycles leads to an increase in the d.c. conductivity of about 102-103, but the effects of chloride salts are not so distinct. A.c. conductivities of the phthalocyanines depend on frequency with the empirical formula σ(ω) = A(T)ωn(T), where n is found to be between 0.37 and 1.20.",

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T1 - Electrical properties of tetraazamacrocycle-substituted phthalocyanines

AU - Öztürk, Z. Ziya

AU - Altindal, Ahmet

AU - Gürek, Ayşegül

AU - Bekaroǧlu, Özer

PY - 1992/10/15

Y1 - 1992/10/15

N2 - D.c. and a.c. conductivities of a copper phthalocyanine substituted with four 15-membered tetraazamacrocycles (1) and its pentanuclear complexes are measured as Au/MPc/Au sandwiches in vacuum and in air. Chemical doping with NOBF4 increases the d.c. conductivity of the order 102. Complexation of the perchlorate salts of NiII, CoII and CuII with the macrocycles leads to an increase in the d.c. conductivity of about 102-103, but the effects of chloride salts are not so distinct. A.c. conductivities of the phthalocyanines depend on frequency with the empirical formula σ(ω) = A(T)ωn(T), where n is found to be between 0.37 and 1.20.

AB - D.c. and a.c. conductivities of a copper phthalocyanine substituted with four 15-membered tetraazamacrocycles (1) and its pentanuclear complexes are measured as Au/MPc/Au sandwiches in vacuum and in air. Chemical doping with NOBF4 increases the d.c. conductivity of the order 102. Complexation of the perchlorate salts of NiII, CoII and CuII with the macrocycles leads to an increase in the d.c. conductivity of about 102-103, but the effects of chloride salts are not so distinct. A.c. conductivities of the phthalocyanines depend on frequency with the empirical formula σ(ω) = A(T)ωn(T), where n is found to be between 0.37 and 1.20.

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DO - 10.1016/0379-6779(92)90028-H

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JO - Synthetic Metals

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Electrical properties of tetraazamacrocycle-substituted phthalocyanines

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