Effects of NCO/OH Ratio and Reactive Diluent Type on the Adhesion Strength of Polyurethane Methacrylates for Cord/Rubber Composites

Zehra Yildiz; Hacer Aysen Onen; Atilla Gungor; Youjiang Wang; Karl Jacob

doi:10.1080/03602559.2017.1364382

Effects of NCO/OH Ratio and Reactive Diluent Type on the Adhesion Strength of Polyurethane Methacrylates for Cord/Rubber Composites

Zehra Yildiz, Hacer Aysen Onen^*, Atilla Gungor, Youjiang Wang, Karl Jacob

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

A series of dual curable polyurethane methacrylate-based oligomers were synthesized by changing the NCO:OH ratio and then were included in adhesive formulations using trimethylolpropane trimethacrylate and tricyclodecane dimethanol diacrylate (TCDDA) as reactive diluents. The effects of NCO:OH ratio and reactive diluent type on the structural properties of UV-cured free films and adhesion properties between polyester cord/rubber surfaces were studied. The highest adhesion strength of the 103 N cm⁻¹ was obtained when the NCO:OH ratio was set as 4 and the TCDDA was used as a reactive diluent.

Original language	English
Pages (from-to)	935-944
Number of pages	10
Journal	Polymer - Plastics Technology and Engineering
Volume	57
Issue number	10
DOIs	https://doi.org/10.1080/03602559.2017.1364382
Publication status	Published - 3 Jul 2018

Bibliographical note

Publisher Copyright:
© 2017 Taylor & Francis.

Funding

This study has been financially supported by Istanbul Technical University Research Fund and The Scientific and Technological Research Council of Turkey (TUBITAK).

Funders	Funder number
Istanbul Technical University Research Fund
TUBITAK
Türkiye Bilimsel ve Teknolojik Araştirma Kurumu

Keywords

Adhesion strength
NCO:OH ratio
polyester cord
reactive diluent
styrene butadiene rubber
UV curing

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10.1080/03602559.2017.1364382

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abstract = "A series of dual curable polyurethane methacrylate-based oligomers were synthesized by changing the NCO:OH ratio and then were included in adhesive formulations using trimethylolpropane trimethacrylate and tricyclodecane dimethanol diacrylate (TCDDA) as reactive diluents. The effects of NCO:OH ratio and reactive diluent type on the structural properties of UV-cured free films and adhesion properties between polyester cord/rubber surfaces were studied. The highest adhesion strength of the 103 N cm−1 was obtained when the NCO:OH ratio was set as 4 and the TCDDA was used as a reactive diluent.",

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AU - Gungor, Atilla

AU - Wang, Youjiang

AU - Jacob, Karl

PY - 2018/7/3

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KW - NCO:OH ratio

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KW - reactive diluent

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Effects of NCO/OH Ratio and Reactive Diluent Type on the Adhesion Strength of Polyurethane Methacrylates for Cord/Rubber Composites

Abstract

Bibliographical note

Funding

Keywords

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