Effect of sonication power on Al2O3 coated LiNi0.5Mn0.3Co0.2O2 cathode material for LIB

Dila Sivlin; Ozgul Keles

doi:10.1007/978-3-319-72362-4_48

Effect of sonication power on Al₂O₃ coated LiNi_0.5Mn_0.3Co_0.2O₂ cathode material for LIB

Dila Sivlin, Ozgul Keles^*

^*Corresponding author for this work

Department of Metallurgical and Materials Engineering

Istanbul Technical University

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

2 Citations (Scopus)

Abstract

Lithium ion batteries are potential energy source of next generation electric vehicles (EVs). However, some problems such as safety, durability, low capacity, cycle life etc. restrict their use in EVs. These problems mostly related with cathode materials, an improvement in cathode materials may cause significant changes in battery performance. In this work, to overcome cycle life problem Al₂O₃ coating on LiNi_0.5Mn_0.3Co_0.2O₂ cathode material produced by sol—gel method. The surface modification of LiNi_0.5Mn_0.3Co_0,2O₂ was started by adding LiNi_0.5Mn_0.3Co_0.2O₂ powders into alumina sol. Then, sonication was started and two different sonication powers were tested (45, 100%). After the second gel is obtained, last heat treatment for Al₂O₃ crystallization was done at 600 °C for 4 h. X—ray diffraction (XRD) measurements showed that the material had a well—ordered layered structure and Al was not in the LiNi_0.5Mn_0.3Co_0.2O₂. Al₂O₃ coated materials show better cycling performance compared to the pristine material. It is believed that, this improvement is caused by the fact that Al₂O₃ layer prevents direct contact between active material and electrolyte and reducing decomposition reactions.

Original language	English
Title of host publication	Energy Technology 2018 - Carbon Dioxide Management and Other Technologies
Editors	Sarma Pisupati, Lei Zhang, Allie Anderson, Shadia Ikhmayies, York R. Smith, Mingming Zhang, Xiaofei Guan, Huimin Lu, Amit Pandey, Dirk Verhulst, Ziqi Sun, Neale R. Neelameggham, Elsa Olivetti, Cong Wang, Donna Post Guillen, John A. Howarter, Tao Wang
Publisher	Springer International Publishing
Pages	515-522
Number of pages	8
ISBN (Print)	9783319723617
DOIs	https://doi.org/10.1007/978-3-319-72362-4_48
Publication status	Published - 2018
Event	Energy Technologies Symposium organized in conjunction with the Annual Meeting and Exhibition, TMS 2018 - Phoenix, United States Duration: 11 Mar 2018 → 15 Mar 2018

Publication series

Name	Minerals, Metals and Materials Series
Volume	Part F6
ISSN (Print)	2367-1181
ISSN (Electronic)	2367-1696

Conference

Conference	Energy Technologies Symposium organized in conjunction with the Annual Meeting and Exhibition, TMS 2018
Country/Territory	United States
City	Phoenix
Period	11/03/18 → 15/03/18

Bibliographical note

Publisher Copyright:
© 2018, The Minerals, Metals & Materials Society.

Keywords

AlO coating
Lithium ion batteries
NMC cathode materials
Surface modification

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1007/978-3-319-72362-4_48

Cite this

Sivlin, D., & Keles, O. (2018). Effect of sonication power on Al₂O₃ coated LiNi_0.5Mn_0.3Co_0.2O₂ cathode material for LIB. In S. Pisupati, L. Zhang, A. Anderson, S. Ikhmayies, Y. R. Smith, M. Zhang, X. Guan, H. Lu, A. Pandey, D. Verhulst, Z. Sun, N. R. Neelameggham, E. Olivetti, C. Wang, D. P. Guillen, J. A. Howarter, & T. Wang (Eds.), Energy Technology 2018 - Carbon Dioxide Management and Other Technologies (pp. 515-522). (Minerals, Metals and Materials Series; Vol. Part F6). Springer International Publishing. https://doi.org/10.1007/978-3-319-72362-4_48

Sivlin, Dila ; Keles, Ozgul. / Effect of sonication power on Al₂O₃ coated LiNi_0.5Mn_0.3Co_0.2O₂ cathode material for LIB. Energy Technology 2018 - Carbon Dioxide Management and Other Technologies. editor / Sarma Pisupati ; Lei Zhang ; Allie Anderson ; Shadia Ikhmayies ; York R. Smith ; Mingming Zhang ; Xiaofei Guan ; Huimin Lu ; Amit Pandey ; Dirk Verhulst ; Ziqi Sun ; Neale R. Neelameggham ; Elsa Olivetti ; Cong Wang ; Donna Post Guillen ; John A. Howarter ; Tao Wang. Springer International Publishing, 2018. pp. 515-522 (Minerals, Metals and Materials Series).

@inproceedings{c57d36b9b0bc42f1adbb0af22a8699ad,

title = "Effect of sonication power on Al2O3 coated LiNi0.5Mn0.3Co0.2O2 cathode material for LIB",

abstract = "Lithium ion batteries are potential energy source of next generation electric vehicles (EVs). However, some problems such as safety, durability, low capacity, cycle life etc. restrict their use in EVs. These problems mostly related with cathode materials, an improvement in cathode materials may cause significant changes in battery performance. In this work, to overcome cycle life problem Al2O3 coating on LiNi0.5Mn0.3Co0.2O2 cathode material produced by sol—gel method. The surface modification of LiNi0.5Mn0.3Co0,2O2 was started by adding LiNi0.5Mn0.3Co0.2O2 powders into alumina sol. Then, sonication was started and two different sonication powers were tested (45, 100%). After the second gel is obtained, last heat treatment for Al2O3 crystallization was done at 600 °C for 4 h. X—ray diffraction (XRD) measurements showed that the material had a well—ordered layered structure and Al was not in the LiNi0.5Mn0.3Co0.2O2. Al2O3 coated materials show better cycling performance compared to the pristine material. It is believed that, this improvement is caused by the fact that Al2O3 layer prevents direct contact between active material and electrolyte and reducing decomposition reactions.",

keywords = "AlO coating, Lithium ion batteries, NMC cathode materials, Surface modification",

author = "Dila Sivlin and Ozgul Keles",

note = "Publisher Copyright: {\textcopyright} 2018, The Minerals, Metals & Materials Society.; Energy Technologies Symposium organized in conjunction with the Annual Meeting and Exhibition, TMS 2018 ; Conference date: 11-03-2018 Through 15-03-2018",

year = "2018",

doi = "10.1007/978-3-319-72362-4_48",

language = "English",

isbn = "9783319723617",

series = "Minerals, Metals and Materials Series",

publisher = "Springer International Publishing",

pages = "515--522",

editor = "Sarma Pisupati and Lei Zhang and Allie Anderson and Shadia Ikhmayies and Smith, {York R.} and Mingming Zhang and Xiaofei Guan and Huimin Lu and Amit Pandey and Dirk Verhulst and Ziqi Sun and Neelameggham, {Neale R.} and Elsa Olivetti and Cong Wang and Guillen, {Donna Post} and Howarter, {John A.} and Tao Wang",

booktitle = "Energy Technology 2018 - Carbon Dioxide Management and Other Technologies",

address = "Switzerland",

}

Sivlin, D & Keles, O 2018, Effect of sonication power on Al₂O₃ coated LiNi_0.5Mn_0.3Co_0.2O₂ cathode material for LIB. in S Pisupati, L Zhang, A Anderson, S Ikhmayies, YR Smith, M Zhang, X Guan, H Lu, A Pandey, D Verhulst, Z Sun, NR Neelameggham, E Olivetti, C Wang, DP Guillen, JA Howarter & T Wang (eds), Energy Technology 2018 - Carbon Dioxide Management and Other Technologies. Minerals, Metals and Materials Series, vol. Part F6, Springer International Publishing, pp. 515-522, Energy Technologies Symposium organized in conjunction with the Annual Meeting and Exhibition, TMS 2018, Phoenix, United States, 11/03/18. https://doi.org/10.1007/978-3-319-72362-4_48

Effect of sonication power on Al₂O₃ coated LiNi_0.5Mn_0.3Co_0.2O₂ cathode material for LIB. / Sivlin, Dila; Keles, Ozgul.
Energy Technology 2018 - Carbon Dioxide Management and Other Technologies. ed. / Sarma Pisupati; Lei Zhang; Allie Anderson; Shadia Ikhmayies; York R. Smith; Mingming Zhang; Xiaofei Guan; Huimin Lu; Amit Pandey; Dirk Verhulst; Ziqi Sun; Neale R. Neelameggham; Elsa Olivetti; Cong Wang; Donna Post Guillen; John A. Howarter; Tao Wang. Springer International Publishing, 2018. p. 515-522 (Minerals, Metals and Materials Series; Vol. Part F6).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Effect of sonication power on Al2O3 coated LiNi0.5Mn0.3Co0.2O2 cathode material for LIB

AU - Sivlin, Dila

AU - Keles, Ozgul

PY - 2018

Y1 - 2018

N2 - Lithium ion batteries are potential energy source of next generation electric vehicles (EVs). However, some problems such as safety, durability, low capacity, cycle life etc. restrict their use in EVs. These problems mostly related with cathode materials, an improvement in cathode materials may cause significant changes in battery performance. In this work, to overcome cycle life problem Al2O3 coating on LiNi0.5Mn0.3Co0.2O2 cathode material produced by sol—gel method. The surface modification of LiNi0.5Mn0.3Co0,2O2 was started by adding LiNi0.5Mn0.3Co0.2O2 powders into alumina sol. Then, sonication was started and two different sonication powers were tested (45, 100%). After the second gel is obtained, last heat treatment for Al2O3 crystallization was done at 600 °C for 4 h. X—ray diffraction (XRD) measurements showed that the material had a well—ordered layered structure and Al was not in the LiNi0.5Mn0.3Co0.2O2. Al2O3 coated materials show better cycling performance compared to the pristine material. It is believed that, this improvement is caused by the fact that Al2O3 layer prevents direct contact between active material and electrolyte and reducing decomposition reactions.

AB - Lithium ion batteries are potential energy source of next generation electric vehicles (EVs). However, some problems such as safety, durability, low capacity, cycle life etc. restrict their use in EVs. These problems mostly related with cathode materials, an improvement in cathode materials may cause significant changes in battery performance. In this work, to overcome cycle life problem Al2O3 coating on LiNi0.5Mn0.3Co0.2O2 cathode material produced by sol—gel method. The surface modification of LiNi0.5Mn0.3Co0,2O2 was started by adding LiNi0.5Mn0.3Co0.2O2 powders into alumina sol. Then, sonication was started and two different sonication powers were tested (45, 100%). After the second gel is obtained, last heat treatment for Al2O3 crystallization was done at 600 °C for 4 h. X—ray diffraction (XRD) measurements showed that the material had a well—ordered layered structure and Al was not in the LiNi0.5Mn0.3Co0.2O2. Al2O3 coated materials show better cycling performance compared to the pristine material. It is believed that, this improvement is caused by the fact that Al2O3 layer prevents direct contact between active material and electrolyte and reducing decomposition reactions.

KW - AlO coating

KW - Lithium ion batteries

KW - NMC cathode materials

KW - Surface modification

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U2 - 10.1007/978-3-319-72362-4_48

DO - 10.1007/978-3-319-72362-4_48

M3 - Conference contribution

AN - SCOPUS:85042288508

SN - 9783319723617

T3 - Minerals, Metals and Materials Series

SP - 515

EP - 522

BT - Energy Technology 2018 - Carbon Dioxide Management and Other Technologies

A2 - Pisupati, Sarma

A2 - Zhang, Lei

A2 - Anderson, Allie

A2 - Ikhmayies, Shadia

A2 - Smith, York R.

A2 - Zhang, Mingming

A2 - Guan, Xiaofei

A2 - Lu, Huimin

A2 - Pandey, Amit

A2 - Verhulst, Dirk

A2 - Sun, Ziqi

A2 - Neelameggham, Neale R.

A2 - Olivetti, Elsa

A2 - Wang, Cong

A2 - Guillen, Donna Post

A2 - Howarter, John A.

A2 - Wang, Tao

PB - Springer International Publishing

T2 - Energy Technologies Symposium organized in conjunction with the Annual Meeting and Exhibition, TMS 2018

Y2 - 11 March 2018 through 15 March 2018

ER -

Sivlin D, Keles O. Effect of sonication power on Al₂O₃ coated LiNi_0.5Mn_0.3Co_0.2O₂ cathode material for LIB. In Pisupati S, Zhang L, Anderson A, Ikhmayies S, Smith YR, Zhang M, Guan X, Lu H, Pandey A, Verhulst D, Sun Z, Neelameggham NR, Olivetti E, Wang C, Guillen DP, Howarter JA, Wang T, editors, Energy Technology 2018 - Carbon Dioxide Management and Other Technologies. Springer International Publishing. 2018. p. 515-522. (Minerals, Metals and Materials Series). doi: 10.1007/978-3-319-72362-4_48