Effect of Mn, Ni, Co transition metal ratios in lithium rich metal oxide cathodes on lithium ion battery performance

Büsra Çetin; Zeyneb Camtakan; Neslihan Yuca

doi:10.1016/j.matpr.2020.03.573

Effect of Mn, Ni, Co transition metal ratios in lithium rich metal oxide cathodes on lithium ion battery performance

Büsra Çetin, Zeyneb Camtakan, Neslihan Yuca^*

^*Corresponding author for this work

Energy Institute

Research output: Contribution to journal › Conference article › peer-review

2 Citations (Scopus)

Abstract

Lithium rich layered metal oxide is a high energy density cathode material for new generation lithium-ion batteries (LIBs). This material has Li [Li_1/3Mn_2/3]O₂and LiMO₂(M: Ni, Co, Mn, Al etc.) structure and exhibit higher irreversible capacity and cycle life than conventional cathode materials. In this study, the stoichiometry of metals in the lithium rich cathode material formulation was investigated by changing Mn, Ni and Co ratios. Li_1.2Mn_0.49+xCo_0.2-2xNi_0.2-2xAl_0.02O₂(xâ€»=â€»0, 0.01, 0.02, 0.03). formulation was used and the prepared lithium rich cathode active powders were structurally characterized by XRD, ICP and NAA. Li-rich cathodes were tested by electrochemical methods, too.

Original language	English
Pages (from-to)	2490-2494
Number of pages	5
Journal	Materials Today: Proceedings
Volume	33
DOIs	https://doi.org/10.1016/j.matpr.2020.03.573
Publication status	Published - 2019
Event	2019 Fall Meeting Metal Oxide- and Oxyhydride-based Nanomaterials for Energy and Environment-related Applications, EMRS 2019 - Warsaw, Poland Duration: 16 Sept 2019 → 19 Sept 2019

Bibliographical note

Publisher Copyright:
© 2019 Elsevier Ltd. All rights reserved.

Keywords

High voltage cathodes
Li-ion batteries
Li-rich cathodes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1016/j.matpr.2020.03.573

Cite this

@article{b3598f7667ed4abfafdb20f693b17411,

title = "Effect of Mn, Ni, Co transition metal ratios in lithium rich metal oxide cathodes on lithium ion battery performance",

abstract = "Lithium rich layered metal oxide is a high energy density cathode material for new generation lithium-ion batteries (LIBs). This material has Li [Li1/3Mn2/3]O2and LiMO2(M: Ni, Co, Mn, Al etc.) structure and exhibit higher irreversible capacity and cycle life than conventional cathode materials. In this study, the stoichiometry of metals in the lithium rich cathode material formulation was investigated by changing Mn, Ni and Co ratios. Li1.2Mn0.49+xCo0.2-2xNi0.2-2xAl0.02O2(x{\^a}€»={\^a}€»0, 0.01, 0.02, 0.03). formulation was used and the prepared lithium rich cathode active powders were structurally characterized by XRD, ICP and NAA. Li-rich cathodes were tested by electrochemical methods, too.",

keywords = "High voltage cathodes, Li-ion batteries, Li-rich cathodes",

author = "B{\"u}sra {\c C}etin and Zeyneb Camtakan and Neslihan Yuca",

note = "Publisher Copyright: {\textcopyright} 2019 Elsevier Ltd. All rights reserved.; 2019 Fall Meeting Metal Oxide- and Oxyhydride-based Nanomaterials for Energy and Environment-related Applications, EMRS 2019 ; Conference date: 16-09-2019 Through 19-09-2019",

year = "2019",

doi = "10.1016/j.matpr.2020.03.573",

language = "English",

volume = "33",

pages = "2490--2494",

journal = "Materials Today: Proceedings",

issn = "2214-7853",

publisher = "Elsevier Ltd",

}

TY - JOUR

T1 - Effect of Mn, Ni, Co transition metal ratios in lithium rich metal oxide cathodes on lithium ion battery performance

AU - Çetin, Büsra

AU - Camtakan, Zeyneb

AU - Yuca, Neslihan

PY - 2019

Y1 - 2019

N2 - Lithium rich layered metal oxide is a high energy density cathode material for new generation lithium-ion batteries (LIBs). This material has Li [Li1/3Mn2/3]O2and LiMO2(M: Ni, Co, Mn, Al etc.) structure and exhibit higher irreversible capacity and cycle life than conventional cathode materials. In this study, the stoichiometry of metals in the lithium rich cathode material formulation was investigated by changing Mn, Ni and Co ratios. Li1.2Mn0.49+xCo0.2-2xNi0.2-2xAl0.02O2(xâ€»=â€»0, 0.01, 0.02, 0.03). formulation was used and the prepared lithium rich cathode active powders were structurally characterized by XRD, ICP and NAA. Li-rich cathodes were tested by electrochemical methods, too.

AB - Lithium rich layered metal oxide is a high energy density cathode material for new generation lithium-ion batteries (LIBs). This material has Li [Li1/3Mn2/3]O2and LiMO2(M: Ni, Co, Mn, Al etc.) structure and exhibit higher irreversible capacity and cycle life than conventional cathode materials. In this study, the stoichiometry of metals in the lithium rich cathode material formulation was investigated by changing Mn, Ni and Co ratios. Li1.2Mn0.49+xCo0.2-2xNi0.2-2xAl0.02O2(xâ€»=â€»0, 0.01, 0.02, 0.03). formulation was used and the prepared lithium rich cathode active powders were structurally characterized by XRD, ICP and NAA. Li-rich cathodes were tested by electrochemical methods, too.

KW - High voltage cathodes

KW - Li-ion batteries

KW - Li-rich cathodes

UR - http://www.scopus.com/inward/record.url?scp=85102432004&partnerID=8YFLogxK

U2 - 10.1016/j.matpr.2020.03.573

DO - 10.1016/j.matpr.2020.03.573

M3 - Conference article

AN - SCOPUS:85102432004

SN - 2214-7853

VL - 33

SP - 2490

EP - 2494

JO - Materials Today: Proceedings

JF - Materials Today: Proceedings

T2 - 2019 Fall Meeting Metal Oxide- and Oxyhydride-based Nanomaterials for Energy and Environment-related Applications, EMRS 2019

Y2 - 16 September 2019 through 19 September 2019

ER -

Effect of Mn, Ni, Co transition metal ratios in lithium rich metal oxide cathodes on lithium ion battery performance

Abstract

Bibliographical note

Keywords

UN SDGs

Access to Document

Other files and links

Fingerprint

Cite this