Effect of group electronegativity on spectroscopic, biological, chromogenic sensing and optical properties of 2-formyl-benzene sulfonic acid sodium salt-based Schiff bases

Elif Akhuseyin Yildiz; Yasemin Pepe; Diğdem Erdener; Ahmet Karatay; Bahadir Boyacioglu; Hüseyin Ünver; Gönül Yapar; Neslihan Demir; Mustafa Yıldız; Ayhan Elmalı

doi:10.1016/j.molstruc.2023.135611

Effect of group electronegativity on spectroscopic, biological, chromogenic sensing and optical properties of 2-formyl-benzene sulfonic acid sodium salt-based Schiff bases

Elif Akhuseyin Yildiz^*, Yasemin Pepe, Diğdem Erdener, Ahmet Karatay, Bahadir Boyacioglu, Hüseyin Ünver, Gönül Yapar, Neslihan Demir, Mustafa Yıldız, Ayhan Elmalı

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

In this study, 2-formylbenzenesulfonic acid sodium salt-based Schiff bases were synthesized from the reactions of 2-formylbenzenesulfonic acid sodium salt with 2-amino-4-chlorophenol and 2-amino-4-methylphenol. The structure of the compounds was determined by FTIR, UV–Vis and NMR spectroscopy methods using both experimental and DFT methods. The anion sensor properties of the compounds were investigated both UV–Vis spectroscopically and calorimetrically. In addition, the antimicrobial activities, interactions with DNA, DNA cleavage and antioxidant activities of Schiff bases were investigated. Additionally, the effects of group electronegativity on the spectroscopic, biological, chromogenic sensing and optical properties of chlorine and methyl side groups and sodium 2-sulfobenzalidene-aminophenol-based Schiff bases were investigated.

Original language	English
Article number	135611
Journal	Journal of Molecular Structure
Volume	1286
DOIs	https://doi.org/10.1016/j.molstruc.2023.135611
Publication status	Published - 15 Aug 2023

Bibliographical note

Publisher Copyright:
© 2023

Keywords

Biological activity
Colorimetric sensor
DFT
Femtosecond transient absorption spectroscopy
Schiff base
Sodium 2-formylbenzenesulfonate

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10.1016/j.molstruc.2023.135611

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Yildiz, E. A., Pepe, Y., Erdener, D., Karatay, A., Boyacioglu, B., Ünver, H., Yapar, G., Demir, N., Yıldız, M., & Elmalı, A. (2023). Effect of group electronegativity on spectroscopic, biological, chromogenic sensing and optical properties of 2-formyl-benzene sulfonic acid sodium salt-based Schiff bases. Journal of Molecular Structure, 1286, Article 135611. https://doi.org/10.1016/j.molstruc.2023.135611

@article{e4626cd1d9b84d2f9a2465301f11fbef,

title = "Effect of group electronegativity on spectroscopic, biological, chromogenic sensing and optical properties of 2-formyl-benzene sulfonic acid sodium salt-based Schiff bases",

abstract = "In this study, 2-formylbenzenesulfonic acid sodium salt-based Schiff bases were synthesized from the reactions of 2-formylbenzenesulfonic acid sodium salt with 2-amino-4-chlorophenol and 2-amino-4-methylphenol. The structure of the compounds was determined by FTIR, UV–Vis and NMR spectroscopy methods using both experimental and DFT methods. The anion sensor properties of the compounds were investigated both UV–Vis spectroscopically and calorimetrically. In addition, the antimicrobial activities, interactions with DNA, DNA cleavage and antioxidant activities of Schiff bases were investigated. Additionally, the effects of group electronegativity on the spectroscopic, biological, chromogenic sensing and optical properties of chlorine and methyl side groups and sodium 2-sulfobenzalidene-aminophenol-based Schiff bases were investigated.",

keywords = "Biological activity, Colorimetric sensor, DFT, Femtosecond transient absorption spectroscopy, Schiff base, Sodium 2-formylbenzenesulfonate",

author = "Yildiz, {Elif Akhuseyin} and Yasemin Pepe and Diğdem Erdener and Ahmet Karatay and Bahadir Boyacioglu and H{\"u}seyin {\"U}nver and G{\"o}n{\"u}l Yapar and Neslihan Demir and Mustafa Yıldız and Ayhan Elmalı",

note = "Publisher Copyright: {\textcopyright} 2023",

year = "2023",

month = aug,

day = "15",

doi = "10.1016/j.molstruc.2023.135611",

language = "English",

volume = "1286",

journal = "Journal of Molecular Structure",

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Yildiz, EA, Pepe, Y, Erdener, D, Karatay, A, Boyacioglu, B, Ünver, H, Yapar, G, Demir, N, Yıldız, M & Elmalı, A 2023, 'Effect of group electronegativity on spectroscopic, biological, chromogenic sensing and optical properties of 2-formyl-benzene sulfonic acid sodium salt-based Schiff bases', Journal of Molecular Structure, vol. 1286, 135611. https://doi.org/10.1016/j.molstruc.2023.135611

Effect of group electronegativity on spectroscopic, biological, chromogenic sensing and optical properties of 2-formyl-benzene sulfonic acid sodium salt-based Schiff bases. / Yildiz, Elif Akhuseyin; Pepe, Yasemin; Erdener, Diğdem et al.
In: Journal of Molecular Structure, Vol. 1286, 135611, 15.08.2023.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Effect of group electronegativity on spectroscopic, biological, chromogenic sensing and optical properties of 2-formyl-benzene sulfonic acid sodium salt-based Schiff bases

AU - Yildiz, Elif Akhuseyin

AU - Pepe, Yasemin

AU - Erdener, Diğdem

AU - Karatay, Ahmet

AU - Boyacioglu, Bahadir

AU - Ünver, Hüseyin

AU - Yapar, Gönül

AU - Demir, Neslihan

AU - Yıldız, Mustafa

AU - Elmalı, Ayhan

PY - 2023/8/15

Y1 - 2023/8/15

N2 - In this study, 2-formylbenzenesulfonic acid sodium salt-based Schiff bases were synthesized from the reactions of 2-formylbenzenesulfonic acid sodium salt with 2-amino-4-chlorophenol and 2-amino-4-methylphenol. The structure of the compounds was determined by FTIR, UV–Vis and NMR spectroscopy methods using both experimental and DFT methods. The anion sensor properties of the compounds were investigated both UV–Vis spectroscopically and calorimetrically. In addition, the antimicrobial activities, interactions with DNA, DNA cleavage and antioxidant activities of Schiff bases were investigated. Additionally, the effects of group electronegativity on the spectroscopic, biological, chromogenic sensing and optical properties of chlorine and methyl side groups and sodium 2-sulfobenzalidene-aminophenol-based Schiff bases were investigated.

AB - In this study, 2-formylbenzenesulfonic acid sodium salt-based Schiff bases were synthesized from the reactions of 2-formylbenzenesulfonic acid sodium salt with 2-amino-4-chlorophenol and 2-amino-4-methylphenol. The structure of the compounds was determined by FTIR, UV–Vis and NMR spectroscopy methods using both experimental and DFT methods. The anion sensor properties of the compounds were investigated both UV–Vis spectroscopically and calorimetrically. In addition, the antimicrobial activities, interactions with DNA, DNA cleavage and antioxidant activities of Schiff bases were investigated. Additionally, the effects of group electronegativity on the spectroscopic, biological, chromogenic sensing and optical properties of chlorine and methyl side groups and sodium 2-sulfobenzalidene-aminophenol-based Schiff bases were investigated.

KW - Biological activity

KW - Colorimetric sensor

KW - DFT

KW - Femtosecond transient absorption spectroscopy

KW - Schiff base

KW - Sodium 2-formylbenzenesulfonate

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DO - 10.1016/j.molstruc.2023.135611

M3 - Article

AN - SCOPUS:85153674295

SN - 0022-2860

VL - 1286

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

M1 - 135611

ER -

Effect of group electronegativity on spectroscopic, biological, chromogenic sensing and optical properties of 2-formyl-benzene sulfonic acid sodium salt-based Schiff bases

Abstract

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