Effect of cetyltrimethylammonium bromide on the migration of polyaromatic hydrocarbons in capillary electrokinetic chromatography

G. Kavran Belin; F. B. Erim; F. O. Gülaçar

doi:10.1016/j.talanta.2005.10.025

Effect of cetyltrimethylammonium bromide on the migration of polyaromatic hydrocarbons in capillary electrokinetic chromatography

G. Kavran Belin^*, F. B. Erim, F. O. Gülaçar

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The separation of different ring numbered polyaromatic hydrocarbons (PAHs) was accomplished by using cetyltrimethylammonium bromide (CTAB) in capillary electrokinetic chromatography. In order to increase the solubilities and selectivities of PAHs, acetonitrile (ACN) was used as an organic modifier. Under the optimised conditions, 11 aromatic compounds were separated within 14.5 min in a running electrolyte containing 10 mM phosphate, 30 mM CTAB, and 40% ACN at pH 6.0. The effects of CTAB and ACN concentrations, voltage and pH on the resolution were investigated. Reproducibilities of migration times range between 0.55 and 1.27 R.S.D.% and peak areas between 1.02 and 7.23 R.S.D.%. Limit of detections (LODs) range between 0.09 and 2.24 μg ml^-1. This new and fast separation method of PAHs was applied to cooked oil sample.

Original language	English
Pages (from-to)	596-600
Number of pages	5
Journal	Talanta
Volume	69
Issue number	3
DOIs	https://doi.org/10.1016/j.talanta.2005.10.025
Publication status	Published - 15 May 2006

Keywords

Capillary electrophoresis
Cationic surfactant
Cetyltrimethylammonium bromide
Cooked oil
PAHs

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10.1016/j.talanta.2005.10.025

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title = "Effect of cetyltrimethylammonium bromide on the migration of polyaromatic hydrocarbons in capillary electrokinetic chromatography",

abstract = "The separation of different ring numbered polyaromatic hydrocarbons (PAHs) was accomplished by using cetyltrimethylammonium bromide (CTAB) in capillary electrokinetic chromatography. In order to increase the solubilities and selectivities of PAHs, acetonitrile (ACN) was used as an organic modifier. Under the optimised conditions, 11 aromatic compounds were separated within 14.5 min in a running electrolyte containing 10 mM phosphate, 30 mM CTAB, and 40% ACN at pH 6.0. The effects of CTAB and ACN concentrations, voltage and pH on the resolution were investigated. Reproducibilities of migration times range between 0.55 and 1.27 R.S.D.% and peak areas between 1.02 and 7.23 R.S.D.%. Limit of detections (LODs) range between 0.09 and 2.24 μg ml-1. This new and fast separation method of PAHs was applied to cooked oil sample.",

keywords = "Capillary electrophoresis, Cationic surfactant, Cetyltrimethylammonium bromide, Cooked oil, PAHs",

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T1 - Effect of cetyltrimethylammonium bromide on the migration of polyaromatic hydrocarbons in capillary electrokinetic chromatography

AU - Belin, G. Kavran

AU - Erim, F. B.

AU - Gülaçar, F. O.

PY - 2006/5/15

Y1 - 2006/5/15

N2 - The separation of different ring numbered polyaromatic hydrocarbons (PAHs) was accomplished by using cetyltrimethylammonium bromide (CTAB) in capillary electrokinetic chromatography. In order to increase the solubilities and selectivities of PAHs, acetonitrile (ACN) was used as an organic modifier. Under the optimised conditions, 11 aromatic compounds were separated within 14.5 min in a running electrolyte containing 10 mM phosphate, 30 mM CTAB, and 40% ACN at pH 6.0. The effects of CTAB and ACN concentrations, voltage and pH on the resolution were investigated. Reproducibilities of migration times range between 0.55 and 1.27 R.S.D.% and peak areas between 1.02 and 7.23 R.S.D.%. Limit of detections (LODs) range between 0.09 and 2.24 μg ml-1. This new and fast separation method of PAHs was applied to cooked oil sample.

AB - The separation of different ring numbered polyaromatic hydrocarbons (PAHs) was accomplished by using cetyltrimethylammonium bromide (CTAB) in capillary electrokinetic chromatography. In order to increase the solubilities and selectivities of PAHs, acetonitrile (ACN) was used as an organic modifier. Under the optimised conditions, 11 aromatic compounds were separated within 14.5 min in a running electrolyte containing 10 mM phosphate, 30 mM CTAB, and 40% ACN at pH 6.0. The effects of CTAB and ACN concentrations, voltage and pH on the resolution were investigated. Reproducibilities of migration times range between 0.55 and 1.27 R.S.D.% and peak areas between 1.02 and 7.23 R.S.D.%. Limit of detections (LODs) range between 0.09 and 2.24 μg ml-1. This new and fast separation method of PAHs was applied to cooked oil sample.

KW - Capillary electrophoresis

KW - Cationic surfactant

KW - Cetyltrimethylammonium bromide

KW - Cooked oil

KW - PAHs

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DO - 10.1016/j.talanta.2005.10.025

M3 - Article

AN - SCOPUS:33646137354

SN - 0039-9140

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SP - 596

EP - 600

JO - Talanta

JF - Talanta

IS - 3

ER -

Effect of cetyltrimethylammonium bromide on the migration of polyaromatic hydrocarbons in capillary electrokinetic chromatography

Abstract

Keywords

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